{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,29]],"date-time":"2026-07-29T11:58:33Z","timestamp":1785326313403,"version":"3.55.0"},"reference-count":32,"publisher":"Wiley","issue":"14","license":[{"start":{"date-parts":[[2026,7,26]],"date-time":"2026-07-26T00:00:00Z","timestamp":1785024000000},"content-version":"vor","delay-in-days":25,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,7,1]],"date-time":"2026-07-01T00:00:00Z","timestamp":1782864000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22279117"],"award-info":[{"award-number":["22279117"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22279118"],"award-info":[{"award-number":["22279118"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["aces.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry \u0097 An Asian Journal"],"published-print":{"date-parts":[[2026,7]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Constructing dual active sites to activate different reactants can effectively lower the reaction energy barrier and significantly improve catalytic activity. Herein, Co\u2500Cu bimetal oxides embedded in the hollow S\u20101 shell were prepared by the impregnation and dissolution\u2013recrystallization method. The catalyst with a Co\/Cu molar ratio of 1:1 exhibited good catalytic activity with a maximum TOF value of 948 mol\n                    <jats:sub>H2<\/jats:sub>\n                    \u2219mol\n                    <jats:sub>cat<\/jats:sub>\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u2219h\n                    <jats:sup>\u22121<\/jats:sup>\n                    . DFT shows that Co sites at CuO\u2500Co\n                    <jats:sub>3<\/jats:sub>\n                    O\n                    <jats:sub>4<\/jats:sub>\n                    interface can efficiently activate the NH\n                    <jats:sub>3<\/jats:sub>\n                    BH\n                    <jats:sub>3<\/jats:sub>\n                    molecule, while Cu sites at the interface effectively activate the H\n                    <jats:sub>2<\/jats:sub>\n                    O molecule. The electron transfer between CuO\u2500Co\n                    <jats:sub>3<\/jats:sub>\n                    O\n                    <jats:sub>4<\/jats:sub>\n                    bimetallic oxides and introduction of hollow S\u20101 supports effectively promote the hydrogen generation and stability via the ensemble effect. This creates a new method to fabricate other hollow zeolite shell\u2010confined metal\/metal oxide catalysts.\n                  <\/jats:p>","DOI":"10.1002\/asia.70894","type":"journal-article","created":{"date-parts":[[2026,7,26]],"date-time":"2026-07-26T10:43:13Z","timestamp":1785062593000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Co\u2500Cu Bimetal Oxides Embedded in Hollow Silicalite\u20101 for Catalytic Hydrogen Generation From Ammonia Borane Hydrolysis"],"prefix":"10.1002","volume":"21","author":[{"given":"Lukuan","family":"Zong","sequence":"first","affiliation":[{"name":"College of Chemistry Zhengzhou University Zhengzhou P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Huinan","family":"Hou","sequence":"additional","affiliation":[{"name":"College of Chemistry Zhengzhou University Zhengzhou P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Huanqing","family":"Guan","sequence":"additional","affiliation":[{"name":"PetroChina Liaoyang Petrochemical Company Liaoyang P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shuling","family":"Liu","sequence":"additional","affiliation":[{"name":"College of Chemistry Zhengzhou University Zhengzhou P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Luyao","family":"Wang","sequence":"additional","affiliation":[{"name":"College of Chemistry Zhengzhou University Zhengzhou P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xianji","family":"Guo","sequence":"additional","affiliation":[{"name":"College of Chemistry Zhengzhou University Zhengzhou P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Huijuan","family":"Wei","sequence":"additional","affiliation":[{"name":"College of Chemistry Zhengzhou University Zhengzhou P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8325-3772","authenticated-orcid":false,"given":"Baojun","family":"Li","sequence":"additional","affiliation":[{"name":"College of Chemistry Zhengzhou University Zhengzhou P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,7,26]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560\u2010025\u201001806\u20109"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apenergy.2025.126089"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1038\/s44359\u2010025\u201000050\u20104"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2025.216871"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ijhydene.2020.04.257"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2025.216445"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.8b06745"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9TA01066A"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2018.05.019"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/er.4290"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp201906n"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1039\/C0DT01633K"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ijhydene.2020.04.061"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2020.118775"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.2c05453"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcis.2021.12.186"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/cnma.202000394"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jechem.2021.04.034"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.5c01890"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.5c00915"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.201802350"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b06511"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.isci.2024.109745"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/crat.200800149"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ica.2009.07.023"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2006.06.004"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.spmi.2013.09.023"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1088\/0031\u20108949\/84\/01\/015801"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1007\/s00339\u2010021\u201004498\u20106"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.201801044"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.2c02089"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202000012"}],"container-title":["Chemistry \u2013 An Asian Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/aces.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/asia.70894","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/aces.onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/asia.70894","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/aces.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/asia.70894","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,29]],"date-time":"2026-07-29T10:59:47Z","timestamp":1785322787000},"score":1,"resource":{"primary":{"URL":"https:\/\/aces.onlinelibrary.wiley.com\/doi\/10.1002\/asia.70894"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,7]]},"references-count":32,"journal-issue":{"issue":"14","published-print":{"date-parts":[[2026,7]]}},"alternative-id":["10.1002\/asia.70894"],"URL":"https:\/\/doi.org\/10.1002\/asia.70894","archive":["Portico"],"relation":{},"ISSN":["1861-4728","1861-471X"],"issn-type":[{"value":"1861-4728","type":"print"},{"value":"1861-471X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,7]]},"assertion":[{"value":"2026-04-16","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-06-28","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-07-26","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e70894"}}