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The reduced products were obtained in good to excellent yields (up to 95%) under mild reaction conditions and exhibits a broad substrate scope, accommodating halogenated, heteroaromatic, and fused nitroarenes. Mechanistic studies, supported by radical\u2010quenching experiments, indicate a multisite proton\u2010coupled electron transfer (MS\u2010PCET) pathway involving key radical intermediates. The application of the method was further extended to reductive cyclization reactions, providing access to biologically relevant N\u2010heterocycles.<\/jats:p>","DOI":"10.1002\/asia.70897","type":"journal-article","created":{"date-parts":[[2026,7,26]],"date-time":"2026-07-26T10:46:31Z","timestamp":1785062791000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Visible\u2010Light\u2010Driven Photoredox\u2010Catalyzed Reduction of Nitro (Hetero)arenes to (Hetero)aryl Amines and Subsequent C\u2500N Bond\u2010Forming Reactions"],"prefix":"10.1002","volume":"21","author":[{"given":"J.","family":"Preety","sequence":"first","affiliation":[{"name":"Laboratory of Sustainable Synthesis, Department of Chemistry SRM Institute of Science and Technology Chengalpet Tamil Nadu India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"T.","family":"Purushothaman","sequence":"additional","affiliation":[{"name":"Laboratory of Sustainable Synthesis, Department of Chemistry SRM Institute of Science and Technology Chengalpet Tamil Nadu India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lekshmi Priya","family":"SL","sequence":"additional","affiliation":[{"name":"Department of Chemistry SRM Institute of Science and Technology Chengalpet Tamil Nadu India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"M.","family":"Shanmugam","sequence":"additional","affiliation":[{"name":"Department of Chemistry SRM Institute of Science and Technology Chengalpet Tamil Nadu India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3114-8265","authenticated-orcid":false,"given":"S.","family":"Mannathan","sequence":"additional","affiliation":[{"name":"Department of Chemistry SRM University\u2010AP Amaravati Andhra Pradesh India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3422-8009","authenticated-orcid":false,"given":"S.","family":"Karthikeyan","sequence":"additional","affiliation":[{"name":"Department of Chemistry SRM Institute of Science and Technology Chengalpet Tamil Nadu India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"B.","family":"Baskar","sequence":"additional","affiliation":[{"name":"Laboratory of Sustainable Synthesis, Department of Chemistry SRM Institute of Science and Technology Chengalpet Tamil Nadu India"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,7,26]]},"reference":[{"key":"e_1_2_5_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0920-5861(97)00005-9"},{"key":"e_1_2_5_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr950083f"},{"key":"e_1_2_5_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/asia.200900018"},{"key":"e_1_2_5_5_1","doi-asserted-by":"publisher","DOI":"10.1007\/s12039-018-1466-8"},{"key":"e_1_2_5_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/B978-0-12-812284-6.00001-9"},{"key":"e_1_2_5_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2018.01.052"},{"key":"e_1_2_5_8_1","unstructured":"R. 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