{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,14]],"date-time":"2026-08-14T08:34:48Z","timestamp":1786696488995,"version":"build-2736575974"},"reference-count":34,"publisher":"Wiley","issue":"15","license":[{"start":{"date-parts":[[2026,8,8]],"date-time":"2026-08-08T00:00:00Z","timestamp":1786147200000},"content-version":"vor","delay-in-days":7,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,8,1]],"date-time":"2026-08-01T00:00:00Z","timestamp":1785542400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21272049"],"award-info":[{"award-number":["21272049"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["aces.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry \u0097 An Asian Journal"],"published-print":{"date-parts":[[2026,8]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    To explore the influence of intermolecular interaction force on the performance of OFET\u2010based sensor and to achieve high detection sensitivity and selectivity, a acrylonitrile bridged thieno[3,2\u2010b]thiophene derivative (2Z,2\u2032Z)\u20103,3\u2032\u2010(2,2\u2032\u2010thieno[3,2\u2010b]thiophene)bis(2\u2010(naphthalen\u20102\u2010yl)acrylonitrile) (TTBNA) was synthesized as the active organic semiconductor material. The single crystal x\u2010ray diffraction analysis reveals that TTBNA forms ordered lamellar stacking by the \u03c0\u2013\u03c0 stacking interactions, and each molecule presents four hydrogen bonds through C\u2500H\n                    <jats:bold>\n                      <jats:sup>\u2026<\/jats:sup>\n                    <\/jats:bold>\n                    N with adjacent two molecules within the molecular layer. The OFET devices exhibit high mobility of 0.444 cm\n                    <jats:sup>2<\/jats:sup>\n                    V\n                    <jats:sup>\u22121<\/jats:sup>\n                    s\n                    <jats:sup>\u22121<\/jats:sup>\n                    and on\/off ratio larger than 10\n                    <jats:sup>7<\/jats:sup>\n                    . The OFET\u2010based sensors show high sensitivity and selectivity for H\n                    <jats:sub>2<\/jats:sub>\n                    S detection and the ratio of current change can still maintain over 2.5 % when the gas concentration lower to 10 ppb level, with the relative sensitivity (RS) up to 250 % ppm\n                    <jats:sup>\u22121<\/jats:sup>\n                    . The excellent sensing characteristics could be caused by the formation of new hydrogen bonding between H\n                    <jats:sub>2<\/jats:sub>\n                    S molecules and N atoms of TTBNA molecules which was confirmed by the theory simulation calculations. This general approach demonstrates that it would be an effective way to improve sensing response capability by introducing variable intermolecular interaction forces in the active simiconductor materials.\n                  <\/jats:p>","DOI":"10.1002\/asia.70939","type":"journal-article","created":{"date-parts":[[2026,8,8]],"date-time":"2026-08-08T12:53:13Z","timestamp":1786193593000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Synthesis and Application of Acrylonitrile Bridged Thieno[3,2\u2010b]Thiophene Derivative for High Performance Organic Field Effect Transistors and H\n                    <sub>2<\/sub>\n                    S Sensor"],"prefix":"10.1002","volume":"21","author":[{"given":"Zichun","family":"Cong","sequence":"first","affiliation":[{"name":"College of Material Chemistry and Chemical Engineering Key Laboratory of Organosilicon Chemistry and Material Technology, Ministry of Education Key Laboratory of Organosilicon Material Technology of Zhejiang Province Hangzhou Normal University  Hangzhou Zhejiang People's Republic of China"},{"name":"College of Chemistry and Chemical Engineering Mudanjiang Normal University  Mudanjiang Heilongjiang People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guanyu","family":"Qiao","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering Shanxi University  Taiyuan Shanxi People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jia","family":"Hao","sequence":"additional","affiliation":[{"name":"College of Material Chemistry and Chemical Engineering Key Laboratory of Organosilicon Chemistry and Material Technology, Ministry of Education Key Laboratory of Organosilicon Material Technology of Zhejiang Province Hangzhou Normal University  Hangzhou Zhejiang People's Republic of 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