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Now we report mono\u2010 and dipotassium\u2010based salts derived from a nitrogen\u2010rich tetrazine framework. Single\u2010crystal X\u2010ray diffraction of dipotassium\n                    <jats:bold>AJE\u20102<\/jats:bold>\n                    reveals extensive K\u2013O and K\u2013N coordination interactions that generate three\u2010dimensional networks reinforced by complementary N\u2500H\u22efO and N\u2500H\u22efN interactions.\n                    <jats:bold>AJE\u20102<\/jats:bold>\n                    exhibits a room\u2010temperature density of 2.01\u00a0g\u00a0cm\n                    <jats:sup>\u22123<\/jats:sup>\n                    , a decomposition onset of\u00a0257\u00b0C, and sensitivity toward mechanical stimuli. These findings highlight the importance of metal\u2010ion\u2010directed assembly in stabilizing nitrogen\u2010rich frameworks and provide insight into the design of potassium\u2010based energetic materials with potential relevance to primary energetics.\n                  <\/jats:p>","DOI":"10.1002\/asia.70963","type":"journal-article","created":{"date-parts":[[2026,8,22]],"date-time":"2026-08-22T13:51:26Z","timestamp":1787406686000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Potassium\u2010Ion\u2010Directed Three\u2010Dimensional Assembly of a Dense and Thermally Robust Nitrogen\u2010Rich Tetrazine Framework"],"prefix":"10.1002","volume":"21","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-3422-5796","authenticated-orcid":false,"given":"Jatinder","family":"Singh","sequence":"first","affiliation":[{"name":"Department of Chemistry University of Idaho  Moscow Idaho 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