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The significant rise in CO\n                    <jats:sub>2<\/jats:sub>\n                    concentrations, predominantly from fossil fuel combustion, has resulted in environmental concerns relating to global warming, ocean acidification, and biodiversity loss. Various mitigation strategies are proposed, including carbon capture and sequestration, carbon capture and utilization, and renewable energy integration. The electrochemical CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction reaction (eCO\n                    <jats:sub>2<\/jats:sub>\n                    RR) is gaining popularity for its ability to produce important fuels and chemicals under mild working conditions. Nonetheless, challenges exist due to high costs, limited catalytic efficiencies, and a suitable electrocatalyst. Cu\u2010based catalysts are the only ones capable of converting CO\n                    <jats:sub>2<\/jats:sub>\n                    into multi\u2010carbon (C\n                    <jats:sub>2<\/jats:sub>\n                    \u2500C\n                    <jats:sub>3<\/jats:sub>\n                    ) products. Other metals such as Au, Ag, Cu, Pd, Sn, and Ni are better suited to CO and formic acid (C1) products. In this review, metallic nanoparticles (NPs) electrocatalysts of Cu, Ag and Au were thoroughly studied for the eCO\n                    <jats:sub>2<\/jats:sub>\n                    RR. The results highlight that metallic NPs with optimized crystal facets, surface states, and nanoscale morphology significantly affect CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction activity and selectivity, demonstrating their potential for sustainable electrocatalytic conversion technologies. Recent techno\u2010economic studies have concluded that product specificity, current density, overpotential, and Faradaic efficiency to be critical for eCO\n                    <jats:sub>2<\/jats:sub>\n                    RR commercial viability.\n                  <\/jats:p>","DOI":"10.1002\/asia.70981","type":"journal-article","created":{"date-parts":[[2026,9,7]],"date-time":"2026-09-07T01:55:51Z","timestamp":1788746151000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Metallic Nanoparticle Catalysts for eCO\n                    <sub>2<\/sub>\n                    RR: Bridging C1 and Multi\u2010Carbon Product Pathways"],"prefix":"10.1002","volume":"21","author":[{"given":"Salka","family":"Debbarma","sequence":"first","affiliation":[{"name":"Department of Chemistry University of Science &amp; Technology Meghalaya  Ri\u2010Bhoi Meghalaya India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kumar Kashyap","family":"Hazarika","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Science &amp; Technology Meghalaya  Ri\u2010Bhoi Meghalaya India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3471-0468","authenticated-orcid":false,"given":"Pankaj","family":"Bharali","sequence":"additional","affiliation":[{"name":"Department of Chemical Sciences Tezpur University  Napaam Assam India"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,9,6]]},"reference":[{"key":"e_1_2_10_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsaem.1c01624"},{"key":"e_1_2_10_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.energyfuels.5c04997"},{"key":"e_1_2_10_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/smtd.201800121"},{"key":"e_1_2_10_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2026.217687"},{"key":"e_1_2_10_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ceja.2020.100013"},{"key":"e_1_2_10_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202514294"},{"key":"e_1_2_10_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202313597"},{"key":"e_1_2_10_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cattod.2020.02.017"},{"key":"e_1_2_10_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202314099"},{"key":"e_1_2_10_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2024.216322"},{"key":"e_1_2_10_12_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-021-00683-1"},{"key":"e_1_2_10_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.4c15927"},{"key":"e_1_2_10_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2025.217064"},{"key":"e_1_2_10_15_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mtsust.2025.101089"},{"key":"e_1_2_10_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.matt.2021.02.021"},{"key":"e_1_2_10_17_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202200586"},{"key":"e_1_2_10_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.enconman.2024.118601"},{"key":"e_1_2_10_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.1c00678"},{"key":"e_1_2_10_20_1","doi-asserted-by":"crossref","unstructured":"A.Arifutzzaman M. 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