{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,14]],"date-time":"2026-09-14T19:05:00Z","timestamp":1789412700914,"version":"build-2803163510"},"reference-count":22,"publisher":"Wiley","issue":"17","license":[{"start":{"date-parts":[[2026,9,4]],"date-time":"2026-09-04T00:00:00Z","timestamp":1788480000000},"content-version":"vor","delay-in-days":3,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,9,1]],"date-time":"2026-09-01T00:00:00Z","timestamp":1788220800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["U2570229"],"award-info":[{"award-number":["U2570229"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003819","name":"Natural Science Foundation of Hubei Province","doi-asserted-by":"publisher","award":["2025EHA051"],"award-info":[{"award-number":["2025EHA051"]}],"id":[{"id":"10.13039\/501100003819","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012226","name":"Fundamental Research Funds for the Central Universities","doi-asserted-by":"publisher","award":["104972026RSCbs0012"],"award-info":[{"award-number":["104972026RSCbs0012"]}],"id":[{"id":"10.13039\/501100012226","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["aces.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry \u0097 An Asian Journal"],"published-print":{"date-parts":[[2026,9]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    In marine environments, epoxy coatings suffer from the penetration of corrosive species through microstructural defects and interfacial discontinuities, causing a rapid degradation in barrier performance during service. Nano\u2010oil can alleviate the aggregation and poor interfacial compatibility of conventional nano filler in epoxy. Here, we synthesized the SiO\n                    <jats:sub>2<\/jats:sub>\n                    nano\u2010oil by \u03b3\u2010Glycidoxypropyltrimethoxysilane functionalization and ring\u2010opening grafting with bis(3\u2010aminopropyl)\u2010terminated polydimethylsiloxane and then incorporated it into epoxy coatings. SiO\n                    <jats:sub>2<\/jats:sub>\n                    \u2010K@PDMS exhibited liquid\u2010like characteristics such as shear\u2010thinning behavior and low surface tension. Electrochemical impedance spectroscopy results showed that the 4 wt% SiO\n                    <jats:sub>2<\/jats:sub>\n                    \u2010K@PDMS\/EP system achieved an initial |\n                    <jats:italic>Z<\/jats:italic>\n                    | at 0.01\u00a0Hz of 1.73 \u00d7 10\n                    <jats:sup>10<\/jats:sup>\n                    \u03a9\u00b7cm\n                    <jats:sup>2<\/jats:sup>\n                    , 436 times that of pure EP. After immersion in 3.5 wt% NaCl solution for 30 d, its |Z| at 0.01\u00a0Hz remained at 3.07 \u00d7 10\n                    <jats:sup>9<\/jats:sup>\n                    \u03a9\u00b7cm\n                    <jats:sup>2<\/jats:sup>\n                    , about 3.88 \u00d7 10\n                    <jats:sup>4<\/jats:sup>\n                    times that of pure EP. Scratched salt spray and fracture surface SEM results showed that SiO\n                    <jats:sub>2<\/jats:sub>\n                    \u2010K@PDMS mitigated corrosion propagation at defect sites and reduced filler aggregation and interfacial voids, which is consistent with its superior long\u2010term impedance retention. In addition, this filler increased the surface hydrophobicity of the coating and reduced the initial adhesion of\n                    <jats:italic>E. coli<\/jats:italic>\n                    . SiO\n                    <jats:sub>2<\/jats:sub>\n                    nano\u2010oil shows great potential for enhancing long\u2010term protection performance of anticorrosion coatings.\n                  <\/jats:p>","DOI":"10.1002\/asia.70982","type":"journal-article","created":{"date-parts":[[2026,9,5]],"date-time":"2026-09-05T04:47:35Z","timestamp":1788583655000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Enhanced Long\u2010Term Barrier and Corrosion Protection of Epoxy Coatings Modified With Silica Nano\u2010Oil"],"prefix":"10.1002","volume":"21","author":[{"given":"Heng","family":"Zhou","sequence":"first","affiliation":[{"name":"State Key Laboratory of Silicate Materials for Architectures &amp; State Key Laboratory of Advanced Technology for Materials Synthesis and Processing &amp; School of Chemistry Chemical Engineering and Life Sciences Wuhan University of Technology  Wuhan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jia\u2010Cong","family":"Tan","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Silicate Materials for Architectures &amp; State Key Laboratory of Advanced Technology for Materials Synthesis and Processing &amp; School of Chemistry Chemical Engineering and Life Sciences Wuhan University of Technology  Wuhan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yao","family":"Huang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Silicate Materials for Architectures &amp; State Key Laboratory of Advanced Technology for Materials Synthesis and Processing &amp; School of Chemistry Chemical Engineering and Life Sciences Wuhan University of Technology  Wuhan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zi\u2010Qian","family":"Yi","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Silicate Materials for Architectures &amp; State Key Laboratory of Advanced Technology for Materials Synthesis and Processing &amp; School of Chemistry Chemical Engineering and Life Sciences Wuhan University of Technology  Wuhan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wen","family":"Zhang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Silicate Materials for Architectures &amp; State Key Laboratory of Advanced Technology for Materials Synthesis and Processing &amp; School of Chemistry Chemical Engineering and Life Sciences Wuhan University of Technology  Wuhan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kai\u2010Qi","family":"Ye","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Silicate Materials for Architectures &amp; State Key Laboratory of Advanced Technology for Materials Synthesis and Processing &amp; School of Chemistry Chemical Engineering and Life Sciences Wuhan University of Technology  Wuhan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shang","family":"Cao","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Silicate Materials for Architectures &amp; State Key Laboratory of Advanced Technology for Materials Synthesis and Processing &amp; School of Chemistry Chemical Engineering and Life Sciences Wuhan University of Technology  Wuhan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4034-5869","authenticated-orcid":false,"given":"Yi","family":"Lu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Silicate Materials for Architectures &amp; State Key Laboratory of Advanced Technology for Materials Synthesis and Processing &amp; School of Chemistry Chemical Engineering and Life Sciences Wuhan University of Technology  Wuhan China"},{"name":"National Energy Key Laboratory for New Hydrogen\u2010Ammonia Energy Technologies Foshan Xianhu Laboratory  Foshan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wei","family":"Geng","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Silicate Materials for Architectures &amp; State Key Laboratory of Advanced Technology for Materials Synthesis and Processing &amp; School of Chemistry Chemical Engineering and Life Sciences Wuhan University of Technology  Wuhan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3454-3604","authenticated-orcid":false,"given":"Xiao\u2010Yu","family":"Yang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Silicate Materials for Architectures &amp; State Key Laboratory of Advanced Technology for Materials Synthesis and Processing &amp; School of Chemistry Chemical Engineering and Life Sciences Wuhan University of Technology  Wuhan China"},{"name":"National Energy Key Laboratory for New Hydrogen\u2010Ammonia Energy Technologies Foshan Xianhu Laboratory  Foshan China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,9,4]]},"reference":[{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.porgcoat.2024.108697"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41529\u2010025\u201000698\u20100"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.pmatsci.2025.101592"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.3390\/polym14153076"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.porgcoat.2023.107561"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsapm.1c01759"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.porgcoat.2026.110071"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.porgcoat.2021.106684"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.3390\/polym15143100"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.porgcoat.2024.108407"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.3390\/polym15153273"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.porgcoat.2023.107522"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.surfcoat.2025.132987"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.diamond.2025.112982"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4LP00239C"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.compositesb.2021.108751"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2RA07794A"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.3390\/polym15081837"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.porgcoat.2024.108680"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.porgcoat.2025.109262"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.3390\/coatings14121487"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.3390\/ma18071531"}],"container-title":["Chemistry \u2013 An Asian Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/aces.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/asia.70982","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/aces.onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/asia.70982","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/aces.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/asia.70982","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,9,14]],"date-time":"2026-09-14T18:30:36Z","timestamp":1789410636000},"score":1,"resource":{"primary":{"URL":"https:\/\/aces.onlinelibrary.wiley.com\/doi\/10.1002\/asia.70982"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,9]]},"references-count":22,"journal-issue":{"issue":"17","published-print":{"date-parts":[[2026,9]]}},"alternative-id":["10.1002\/asia.70982"],"URL":"https:\/\/doi.org\/10.1002\/asia.70982","archive":["Portico"],"relation":{},"ISSN":["1861-4728","1861-471X"],"issn-type":[{"value":"1861-4728","type":"print"},{"value":"1861-471X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,9]]},"assertion":[{"value":"2026-05-22","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-08-28","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-09-04","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e70982"}}