{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,29]],"date-time":"2026-09-29T12:58:06Z","timestamp":1790686686445,"version":"4.1.0"},"reference-count":35,"publisher":"Wiley","issue":"18","license":[{"start":{"date-parts":[[2026,9,24]],"date-time":"2026-09-24T00:00:00Z","timestamp":1790208000000},"content-version":"vor","delay-in-days":23,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,9,1]],"date-time":"2026-09-01T00:00:00Z","timestamp":1788220800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["aces.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry \u0097 An Asian Journal"],"published-print":{"date-parts":[[2026,9]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    The endogenous hydrogen sulfide (H\n                    <jats:sub>2<\/jats:sub>\n                    S) is a vital signaling molecule and plays an important role in the physiological processes. Its abnormal level can cause various detrimental effects. Thus, there is a bourgeoning need to develop facile and sensitive methods for detecting H\n                    <jats:sub>2<\/jats:sub>\n                    S in various biological samples. Herein, a fluorescence\u2010based sensing platform has been developed for the ultrasensitive detection of H\n                    <jats:sub>2<\/jats:sub>\n                    S using an aggregation\u2010induced emission (AIE) active dicyanoisophorone derivative with\n                    <jats:italic>o\u2010<\/jats:italic>\n                    vanillin (DSVL). AIE luminogen (AIEgen) fluorescence emission at 530\u00a0nm was quenched selectively by H\n                    <jats:sub>2<\/jats:sub>\n                    S, which enables its detection with a detection limit of 3.88\u00a0\u00b5M. Interestingly, when the probe DSVL was interacted with bovine serum albumin\u2010stabilized silver nanoclusters (BSA\u2010AgNCs), the formation of nanocomposite BSA\u2010AgNCs_DSVL resulted a significant enhancement in the relative quantum yield of DSVL from 31.88% to 83.84%. The highly fluorescent nanocomposite BSA\u2010AgNCs_DSVL showed an improved sensitivity with the detection limit down to 0.86\u00a0nM. Finally, the analytical utility was examined by detecting H\n                    <jats:sub>2<\/jats:sub>\n                    S in real samples, such as blood serum and vegetable extracts.\n                  <\/jats:p>","DOI":"10.1002\/asia.70999","type":"journal-article","created":{"date-parts":[[2026,9,24]],"date-time":"2026-09-24T13:46:51Z","timestamp":1790257611000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["BSA\u2010Stabilized Silver Nanoclusters Enhanced Fluorescence of a Dicyanoisophorone Derivative With\n                    <i>o\u2010<\/i>\n                    Vanillin for Sensitive Detection of Hydrogen Sulfide (H\n                    <sub>2<\/sub>\n                    S)"],"prefix":"10.1002","volume":"21","author":[{"given":"Rajanee","family":"Nakum","sequence":"first","affiliation":[{"name":"Department of Chemistry Sardar Vallabhbhai National Institute of Technology  Surat Gujarat India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Suban K","family":"Sahoo","sequence":"additional","affiliation":[{"name":"Department of Chemistry Sardar Vallabhbhai National Institute of Technology  Surat Gujarat India"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,9,24]]},"reference":[{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.3c00683"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/bs.mie.2014.11.025"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202305866"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.redox.2020.101772"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.neurot.2025.e00755"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssensors.4c02033"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.analchem.7b05421"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacsau.3c00427"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.aca.2018.08.054"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4CS00298A"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/jo01134a023"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.iecr.5c01869"},{"issue":"1","key":"e_1_2_7_14_1","article-title":"A Multifunctional Dicyanoisophorone\u2010Based Fluorescent Probe for Zn2+ and Pyrophosphate Detection: Practical Applications in Water, Living Sprout, and Cell Imaging","volume":"344","author":"Liu L.","year":"2025","journal-title":"Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.microc.2025.114188"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja207851s"},{"issue":"1","key":"e_1_2_7_17_1","article-title":"Comprehensive Insights About Accurate Susceptibility Detection Toward Hydrogen Sulfide for Food Safety and Disease Diagnosis","volume":"348","author":"Zeng X.","year":"2025","journal-title":"Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.niox.2025.04.004"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3NJ01700A"},{"issue":"2","key":"e_1_2_7_20_1","article-title":"The Dicyanoisophorone Scaffold: A Versatile Platform for Near\u2010Infrared, Large Stokes Shift Fluorescent Probes in Sensing and Bioimaging","volume":"1351","author":"Lin B.","year":"2025","journal-title":"Journal of Molecular Structure"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1080\/10408347.2024.2354328"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1007\/s10895\u2010024\u201003601\u20103"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8TB02205D"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2023.215193"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.dyepig.2013.05.031"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.aca.2022.340538"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jlumin.2017.10.010"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp412279m"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1021\/jo400116j"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.saa.2025.127297"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1021\/ac502941h"},{"key":"e_1_2_7_32_1","unstructured":"M.Frisch G.Trucks H.Schlegel et\u00a0al. \u201cGaussian 09W Gaussian Inc. 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