{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,14]],"date-time":"2026-10-14T13:44:36Z","timestamp":1791985476870,"version":"4.4.0"},"reference-count":82,"publisher":"Wiley","issue":"19","license":[{"start":{"date-parts":[[2026,9,29]],"date-time":"2026-09-29T00:00:00Z","timestamp":1790640000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,9,29]],"date-time":"2026-09-29T00:00:00Z","timestamp":1790640000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001501","name":"University Grants Commission","doi-asserted-by":"publisher","award":["ANRF\/ARG\/2025\/001957\/CS"],"award-info":[{"award-number":["ANRF\/ARG\/2025\/001957\/CS"]}],"id":[{"id":"10.13039\/501100001501","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["aces.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry \u0097 An Asian Journal"],"published-print":{"date-parts":[[2026,10]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    The integration of protein secondary structures with metal ions offers a promising strategy for designing highly ordered self\u2010assembled structures with enhanced stability and functionality. The nature of the amino acids plays a crucial role in dictating the secondary structures of peptides. Here, we report highly stable and porous ZnCl\n                    <jats:sub>2<\/jats:sub>\n                    \u2010helix\u2010frameworks from the \u03b1,\u03b3\u2010hybrid peptide containing terminal 4\u2010pyridyl groups, whereas the control \u03b1\u2010peptide showed a ZnCl\n                    <jats:sub>2<\/jats:sub>\n                    \u2010coordinated left\u2010handed superhelix network. The stable, porous 12\u2010helix frameworks of the \u03b1,\u03b3\u2010hybrid peptide have been further explored as hosts to encapsulate guest solvent molecules such as nitromethane and 1,2\u2010dichloroethane after soaking the metal\u2010coordinated\u2010helix\u2010frameworks. Overall, the substitution of an \u03b1\u2010amino acid in a short \u03b1\u2010peptide sequence with a \u03b3\u2010amino acid leads to a change in the helical structure as well as in its coordination ability.\n                  <\/jats:p>","DOI":"10.1002\/asia.71000","type":"journal-article","created":{"date-parts":[[2026,9,30]],"date-time":"2026-09-30T05:29:58Z","timestamp":1790746198000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["The Structural Distinction of \u03b1\u2010 and \u03b1,\u03b3\u2010Hybrid Peptides Influences Their Zn(II)\u2010Coordinated Supramolecular Organization"],"prefix":"10.1002","volume":"21","author":[{"given":"Sanjit","family":"Dey","sequence":"first","affiliation":[{"name":"Department of Chemistry Indian Institute of Science Education and Research (IISER)  Pune India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Souvik","family":"Roy","sequence":"additional","affiliation":[{"name":"Department of Chemistry Indian Institute of Science Education and Research (IISER)  Pune India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sandip U.","family":"Toraskar","sequence":"additional","affiliation":[{"name":"Department of Chemistry Indian Institute of Science Education and Research (IISER)  Pune India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8156-9271","authenticated-orcid":false,"given":"Hosahudya N.","family":"Gopi","sequence":"additional","affiliation":[{"name":"Department of Chemistry Indian Institute of Science Education and Research (IISER)  Pune India"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,9,29]]},"reference":[{"key":"e_1_2_8_2_1","volume-title":"Proteins: Structure and Molecular Properties","author":"Creighton T. E.","year":"1993"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja3088407"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr040648k"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/ar800064f"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja200222n"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1038\/nrm3810"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1038\/nrm2101"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200802808"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1038\/nrd3050"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202206795"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/bip.22058"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8CS00115D"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.0c00690"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1038\/366324a0"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/nn300015g"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5CS00941C"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201801001"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201602624"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.3390\/polym15051068"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41570\u2010020\u20100215\u2010y"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.1c00712"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja0775016"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1016\/S1074\u20105521(01)00073\u20104"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.bbrc.2016.03.042"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b00651"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9CC03496J"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja4074529"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsomega.2c01669"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201509304"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b08163"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b06708"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja804942w"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja8088845"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja103148t"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.biochem.5b00502"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1190672"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.1871"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2019.12.009"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2020.07.002"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c11793"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c08487"},{"key":"e_1_2_8_43_1","doi-asserted-by":"publisher","DOI":"10.1002\/cbic.202200448"},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202108364"},{"key":"e_1_2_8_45_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1CC03101E"},{"key":"e_1_2_8_46_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja8009555"},{"key":"e_1_2_8_47_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b01541"},{"key":"e_1_2_8_48_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c03094"},{"key":"e_1_2_8_49_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.biomac.3c01418"},{"key":"e_1_2_8_50_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c04078"},{"key":"e_1_2_8_51_1","doi-asserted-by":"publisher","DOI":"10.1002\/cplu.202000730"},{"key":"e_1_2_8_52_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5CS00234F"},{"key":"e_1_2_8_53_1","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.1894"},{"key":"e_1_2_8_54_1","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.1146"},{"key":"e_1_2_8_55_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsabm.8b00513"},{"key":"e_1_2_8_56_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201801247"},{"key":"e_1_2_8_57_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsomega.9b03939"},{"key":"e_1_2_8_58_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr300014x"},{"key":"e_1_2_8_59_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4CS90059F"},{"key":"e_1_2_8_60_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1217544"},{"key":"e_1_2_8_61_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201810849"},{"key":"e_1_2_8_62_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202015838"},{"key":"e_1_2_8_63_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4CC05770H"},{"key":"e_1_2_8_64_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201064544\u20102"},{"key":"e_1_2_8_65_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202305753"},{"key":"e_1_2_8_66_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c03970"},{"key":"e_1_2_8_67_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202513629"},{"key":"e_1_2_8_68_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201203929"},{"key":"e_1_2_8_69_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201605753"},{"key":"e_1_2_8_70_1","doi-asserted-by":"publisher","DOI":"10.1039\/C2OB26805A"},{"key":"e_1_2_8_71_1","doi-asserted-by":"publisher","DOI":"10.1039\/c2cc32911e"},{"key":"e_1_2_8_72_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201204436"},{"key":"e_1_2_8_73_1","doi-asserted-by":"publisher","DOI":"10.1021\/jo052340e"},{"key":"e_1_2_8_74_1","doi-asserted-by":"publisher","DOI":"10.1002\/asia.201901411"},{"key":"e_1_2_8_75_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr000053z"},{"key":"e_1_2_8_76_1","doi-asserted-by":"publisher","DOI":"10.1107\/S1600576721002910"},{"key":"e_1_2_8_77_1","doi-asserted-by":"publisher","DOI":"10.1021\/ol300987d"},{"key":"e_1_2_8_78_1","doi-asserted-by":"publisher","DOI":"10.1002\/hlca.201200436"},{"key":"e_1_2_8_79_1","doi-asserted-by":"publisher","DOI":"10.1021\/ol500307p"},{"key":"e_1_2_8_80_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b06177"},{"key":"e_1_2_8_81_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja907233q"},{"key":"e_1_2_8_82_1","doi-asserted-by":"publisher","DOI":"10.1107\/S0108767390000277"},{"key":"e_1_2_8_83_1","first-page":"C34","article-title":"PLATON, an Integrated Tool for the Analysis of the Results of a Single Crystal Structure Determination","volume":"46","author":"Spek A. L.","year":"1990","journal-title":"Acta Crystallographica"}],"container-title":["Chemistry \u2013 An Asian Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/aces.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/asia.71000","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/aces.onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/asia.71000","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/aces.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/asia.71000","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,10,14]],"date-time":"2026-10-14T12:46:08Z","timestamp":1791981968000},"score":1,"resource":{"primary":{"URL":"https:\/\/aces.onlinelibrary.wiley.com\/doi\/10.1002\/asia.71000"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,9,29]]},"references-count":82,"journal-issue":{"issue":"19","published-print":{"date-parts":[[2026,10]]}},"alternative-id":["10.1002\/asia.71000"],"URL":"https:\/\/doi.org\/10.1002\/asia.71000","archive":["Portico"],"relation":{},"ISSN":["1861-4728","1861-471X"],"issn-type":[{"value":"1861-4728","type":"print"},{"value":"1861-471X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,9,29]]},"assertion":[{"value":"2026-05-09","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-09-17","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-09-29","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e71000"}}