{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,6,18]],"date-time":"2026-06-18T15:56:07Z","timestamp":1781798167988,"version":"3.54.5"},"reference-count":62,"publisher":"Wiley","issue":"3","license":[{"start":{"date-parts":[[2025,11,17]],"date-time":"2025-11-17T00:00:00Z","timestamp":1763337600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2025,11,17]],"date-time":"2025-11-17T00:00:00Z","timestamp":1763337600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["iubmb.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Biotech and App Biochem"],"published-print":{"date-parts":[[2026,6]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Azo\u2010oxime ligands, namely, Ar\u2010HL\n                    <jats:sup>Ph<\/jats:sup>\n                    ,\n                    <jats:bold>1<\/jats:bold>\n                    (Ar\u00a0=\u00a0phenyl, pyridyl, and naphthyl) and Ar\u2044\u2010HL\n                    <jats:sup>py<\/jats:sup>\n                    <jats:bold>2<\/jats:bold>\n                    (Ar\u2044\u00a0=\u00a0phenyl,\n                    <jats:italic>p<\/jats:italic>\n                    \u2010tolyl) were used to synthesize three trinuclear mixed valence iron complexes of type [Fe\n                    <jats:sup>III<\/jats:sup>\n                    (Fe\n                    <jats:sup>II<\/jats:sup>\n                    (Ar\u2010L\n                    <jats:sup>Ph<\/jats:sup>\n                    )\n                    <jats:sub>3<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    ]ClO\n                    <jats:sub>4<\/jats:sub>\n                    <jats:bold>\n                      3\n                      <jats:sup>+<\/jats:sup>\n                      ClO\n                      <jats:sub>4<\/jats:sub>\n                      <jats:sup>\u2212<\/jats:sup>\n                    <\/jats:bold>\n                    and four bis\u2010chelates [M\n                    <jats:sup>II<\/jats:sup>\n                    (Ar\u2044\u2010L\n                    <jats:sup>py<\/jats:sup>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    ] (M\u00a0=\u00a0Fe,\n                    <jats:bold>4<\/jats:bold>\n                    and M\u00a0=\u00a0Mn,\n                    <jats:bold>5<\/jats:bold>\n                    ). The SCXRD structures of [Mn\n                    <jats:sup>II<\/jats:sup>\n                    (Ar\u2044\u2010L\n                    <jats:sup>py<\/jats:sup>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    ] and [Fe\n                    <jats:sup>II<\/jats:sup>\n                    (Ar\u2044\u2010L\n                    <jats:sup>py<\/jats:sup>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    ] (Ar\u2044\u00a0=\u00a0\n                    <jats:italic>p<\/jats:italic>\n                    \u2010tolyl) are consistent with the theoretically optimized structures. The N\u2500N (azo) distances are longer in comparison to their nickel(II) congeners and the order of average N\u2500N (azo) lengths of [Ni\n                    <jats:sup>II<\/jats:sup>\n                    (Ar\u2044\u2010L\n                    <jats:sup>py<\/jats:sup>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    ]\u00a0&lt;\u00a0[Fe\n                    <jats:sup>II<\/jats:sup>\n                    (Ar\u2044\u2010L\n                    <jats:sup>py<\/jats:sup>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    ]\u00a0&lt;\u00a0[Mn\n                    <jats:sup>II<\/jats:sup>\n                    (Ar\u2044\u2010L\n                    <jats:sup>py<\/jats:sup>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    ], reported earlier. This is ascribed to greater \u03c0\u2010acceptance by azo function with Ni(II) \u2192 Fe(II) \u2192 Mn(II). The nature of the FMOs of [Mn\n                    <jats:sup>II<\/jats:sup>\n                    (Ar\u2044\u2010L\n                    <jats:sup>py<\/jats:sup>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    ] and [Fe\n                    <jats:sup>II<\/jats:sup>\n                    (Ar\u2044\u2010L\n                    <jats:sup>py<\/jats:sup>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    ] (Ar\u2044\u00a0=\u00a0\n                    <jats:italic>p<\/jats:italic>\n                    \u2010tolyl) has been inspected, and their absorption spectra were supported by TDDFT analysis. The complexes were subjected to anti\u2010bacterial screening against two Gram\u2010positive, namely,\n                    <jats:italic>Streptococcus mutans<\/jats:italic>\n                    and\n                    <jats:italic>Staphylococcus aureus<\/jats:italic>\n                    and two Gram\u2010negative strains, namely,\n                    <jats:italic>Escherichia. coli, and Salmonella<\/jats:italic>\n                    sp. and their mode of action have also been detected. IC\n                    <jats:sub>50<\/jats:sub>\n                    values of the complexes for all four bacterial strains designates that Gram\u2010negative bacterial strains were more susceptible than the Gram\u2010positive\n                    <jats:italic>strains<\/jats:italic>\n                    and among the two Gram\u2010negative strains,\n                    <jats:italic>Salmonella<\/jats:italic>\n                    sp. was more affected than\n                    <jats:italic>Escherichia coli<\/jats:italic>\n                    . All seven complexes have significant broad\u2010spectrum antibacterial potential for MDR bacterial strains, and the mode of antibacterial action appears to progress via a versatile molecular mechanism, including all the biomolecular fronts, namely, proteins, lipids, and nucleic acids damage.\n                  <\/jats:p>","DOI":"10.1002\/bab.70090","type":"journal-article","created":{"date-parts":[[2025,11,18]],"date-time":"2025-11-18T05:54:57Z","timestamp":1763445297000},"page":"1217-1240","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Synthesis, Molecular Structure, and Antibacterial Efficacies of Transition Metal Azo\u2010Oximates of Fe(II) and Mn(II), a Sustainable Solution to Multidrug Resistance in 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