{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,8]],"date-time":"2025-10-08T22:50:22Z","timestamp":1759963822088,"version":"build-2065373602"},"reference-count":23,"publisher":"Wiley","issue":"2","license":[{"start":{"date-parts":[[2008,9,11]],"date-time":"2008-09-11T00:00:00Z","timestamp":1221091200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Luminescence"],"published-print":{"date-parts":[[2009,3]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>In this paper, oscillating chemiluminescence (CL), 1,10\u2010phenanthroline H<jats:sub>2<\/jats:sub>O<jats:sub>2<\/jats:sub>\u2013KSCN\u2013CuSO<jats:sub>4<\/jats:sub>\u2013NaOH system, was studied in a batch reactor. The system described is a novel, slowly damped oscillating CL system, generated by coupling the well\u2010known Epstein\u2013Orban, H<jats:sub>2<\/jats:sub>O<jats:sub>2<\/jats:sub>\u2013KSCN\u2013CuSO<jats:sub>4<\/jats:sub>\u2013NaOH chemical oscillator reaction with the CL reaction involving the oxidation of 1,10\u2010phenanthroline by hydrogen peroxide, catalyzed by copper(II) in alkaline medium. In this system, the CL reaction acts as a detector or indicator system of the far\u2010from\u2010equilibrium dynamic system. Narrow and slightly asymmetric light pulses of 1.2\u00a0s half\u2010width are emitted at 440\u00a0nm with an emitted light time of 200\u20131000\u00a0s, induction period of 3.5\u2013357\u00a0s and oscillation period of 28\u2013304\u00a0s depending on the reagent concentrations. In this report the effect of the concentration variation of components involved in the oscillating CL system on the induction period, the oscillation period and amplitude was investigated and the parameters were plotted with respect to reagent concentrations. Copper concentration showed a significant effect on the oscillation period. The possible mechanism for the oscillating CL reaction was also discussed. Copyright \u00a9 2008 John Wiley &amp; Sons, Ltd.<\/jats:p>","DOI":"10.1002\/bio.1084","type":"journal-article","created":{"date-parts":[[2008,9,11]],"date-time":"2008-09-11T11:15:33Z","timestamp":1221131733000},"page":"115-122","source":"Crossref","is-referenced-by-count":9,"title":["1,10\u2010Phenanthroline\u2013H<sub>2<\/sub>O<sub>2<\/sub>\u2013KSCN\u2013CuSO<sub>4<\/sub>\u2013NaOH oscillating chemiluminescence system"],"prefix":"10.1002","volume":"24","author":[{"given":"M. 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