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A possible mechanism was proposed for this reaction based on UV\/Vis absorption, fluorescence and the generated CL emission spectra. However, it was observed that ethanol had a remarkable inhibition effect on this system. This effect was exploited in the determination of ethanol within the concentration range 12\u2013300\u2009\u00b5g\/L, with detection at 4.3\u2009\u00b5g\/L. In order to evaluate the capability of presented method, it was satisfactorily utilized in the determination of alcohol in real samples. 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