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Based on FRET quenching theory, we designed a method to detect the concentration of silver ions (Ag<jats:sup>+<\/jats:sup>). The results revealed a good linear trend over Ag<jats:sup>+<\/jats:sup> concentrations in the range 0.01\u20138.96\u2009nmol\/L, a range that was larger than with other methods; the quenching coefficient is 0.442. The FRET mechanism and physical mechanisms responsible for dynamic quenching are also discussed. 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