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A novel photochemical approach was introduced for the growth of CdS QDs and this approach was used to grow a CdS shell around CdSe cores for the formation of a CdSe\/CdS core\u2013shell structure. The core\u2013shells were structurally verified using X\u2010ray diffraction, transmission electron microscopy and FTIR (Fourier\u2010transform infrared (FTIR)) spectroscopy. The optical properties of the samples were examined by means of UV\u2013Vis and photoluminescence (PL) spectroscopy. It was found that CdS QDs emit a broad band white luminescence between 400 to 700\u00a0nm with a peak located at about 510\u00a0nm. CdSe QDs emission contained a broad band resulting from trap states between 450 to 800\u00a0nm with a peak located at 600\u00a0nm. After CdS shell growth, trap states emission was considerably quenched and a near band edge emission was appeared about 480\u00a0nm. Optical studies revealed that the core\u2013shell QDs possess strong ultraviolet (UV)\u00a0\u2212\u00a0visible light photocatalytic activity. CdSe\/CdS core\u2013shell QDs, showed an enhancement in photodegradation of Methyl orange (MO) compared with CdSe QDs.<\/jats:p>","DOI":"10.1002\/bio.3300","type":"journal-article","created":{"date-parts":[[2017,4,5]],"date-time":"2017-04-05T15:13:39Z","timestamp":1491405219000},"page":"1137-1144","source":"Crossref","is-referenced-by-count":28,"title":["CdSe and CdSe\/CdS core\u2013shell QDs: New approach for synthesis, investigating optical properties and application in pollutant degradation"],"prefix":"10.1002","volume":"32","author":[{"given":"S.","family":"Abbasi","sequence":"first","affiliation":[{"name":"Department of Physics, Faculty of Science Vali\u2010e\u2010Asr University  Rafsanjan Iran"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4129-7328","authenticated-orcid":false,"given":"M.","family":"Molaei","sequence":"additional","affiliation":[{"name":"Department of Physics, Faculty of Science Vali\u2010e\u2010Asr University  Rafsanjan Iran"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"M.","family":"Karimipour","sequence":"additional","affiliation":[{"name":"Department of Physics, Faculty of Science Vali\u2010e\u2010Asr University  Rafsanjan Iran"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2017,4,5]]},"reference":[{"key":"e_1_2_6_2_1","volume":"29","author":"Molaei M.","year":"2016","journal-title":"Mod. 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