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Even a very small amount of mercury can cause serious harm to human beings. Herein, we reported a new carbonothioate\u2010based fluorescent probe for the detection of Hg<jats:sup>2+<\/jats:sup> without interference from other metal ions. This probe possessed a very large Stokes shift (192\u00a0nm), which could improve the detection sensitivity by minimizing the interferences resulted from self\u2010absorption or auto\u2010fluorescence. With the addition of Hg<jats:sup>2+<\/jats:sup> to the probe solution, considerable fluorescence enhancement was observed. Additionally, the Hg<jats:sup>2+<\/jats:sup> concentration of 0\u201316\u00a0\u03bcM and fluorescence intensity showed a good linear relationship (y\u00a0=\u00a022106\u00d7\u00a0+\u00a053108, <jats:italic>R<\/jats:italic><jats:sup>2<\/jats:sup>\u00a0=\u00a00.9955). Finally, the proposed probe was used to detect Hg<jats:sup>2+<\/jats:sup> in real water samples, and its result was satisfactory. Therefore, our proposed probe would provide a promising method for the determination of Hg<jats:sup>2+<\/jats:sup> in the environment.<\/jats:p>","DOI":"10.1002\/bio.3404","type":"journal-article","created":{"date-parts":[[2017,10,25]],"date-time":"2017-10-25T10:36:57Z","timestamp":1508927817000},"page":"219-224","source":"Crossref","is-referenced-by-count":18,"title":["A carbonothioate\u2010based highly selective fluorescent probe with a large Stokes shift for detection of Hg<sup>2+<\/sup>"],"prefix":"10.1002","volume":"33","author":[{"given":"Jing","family":"Xu","sequence":"first","affiliation":[{"name":"School of Water and Soil Conservation Beijing Forestry University  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhenghe","family":"Xu","sequence":"additional","affiliation":[{"name":"School of Resources and Environment University of Jinan, Shandong Provincial Engineering Technology Research Center for Ecological Carbon Sink and Capture Utilization  Jinan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zuokai","family":"Wang","sequence":"additional","affiliation":[{"name":"School of Resources and Environment University of Jinan, Shandong Provincial Engineering Technology Research Center for Ecological Carbon Sink and Capture Utilization  Jinan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6506-4783","authenticated-orcid":false,"given":"Caiyun","family":"Liu","sequence":"additional","affiliation":[{"name":"School of Resources and Environment University of Jinan, Shandong Provincial Engineering Technology Research Center for Ecological Carbon Sink and Capture Utilization  Jinan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6221-2071","authenticated-orcid":false,"given":"Baocun","family":"Zhu","sequence":"additional","affiliation":[{"name":"School of Resources and Environment University of Jinan, Shandong Provincial Engineering Technology Research Center for Ecological Carbon Sink and Capture Utilization  Jinan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiuru","family":"Wang","sequence":"additional","affiliation":[{"name":"School of Water and Soil Conservation Beijing Forestry University  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kun","family":"Wang","sequence":"additional","affiliation":[{"name":"School of Resources and Environment University of Jinan, Shandong Provincial Engineering Technology Research Center for Ecological Carbon Sink and Capture Utilization  Jinan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiangting","family":"Wang","sequence":"additional","affiliation":[{"name":"School of Resources and Environment University of Jinan, Shandong Provincial Engineering Technology Research Center for Ecological Carbon Sink and Capture Utilization  Jinan 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