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Parameters effective in laser assisted synthesis of NPs such as irradiation time and laser shot repetition rate were optimized. Photoluminescence (PL) spectra of ZnO NPs showed a broad emission with two trap state peaks located at 442 and 485\u00a0nm related to electronic transition from zinc interstitial level (I<jats:sub>Zn<\/jats:sub>) to zinc vacancy level (V<jats:sub>Zn<\/jats:sub>) and electronic transition from conduction band to the oxygen vacancy level (V<jats:sub>O<\/jats:sub>), respectively. For ZnO:Cu NPs, trap state emissions disappeared completely and a copper (Cu)\u2010related emission appeared. PL intensity of Cu\u2010related emission increased with the increase in concentration of Cu<jats:sup>2+<\/jats:sup>, so that for molar ratio of Cu:Zn 2%, optimal value of PL intensity was obtained. The photocatalytic activity of Cu\u2010doped ZnO revealed 50 and 100% increasement than that of undoped NPs under UV and visible irradiation, respectively. The enhanced photocatalytic activity could be attributed to smaller crystal size, as well as creation of impurity acceptor levels (T<jats:sub>2<\/jats:sub>) inside the ZnO energy band gap.<\/jats:p>","DOI":"10.1002\/bio.3436","type":"journal-article","created":{"date-parts":[[2017,12,28]],"date-time":"2017-12-28T02:49:12Z","timestamp":1514429352000},"page":"475-485","source":"Crossref","is-referenced-by-count":5,"title":["Rapid, controllable, one\u2010pot and room\u2010temperature aqueous synthesis of ZnO:Cu nanoparticles by pulsed UV laser and its application for photocatalytic degradation of methyl orange"],"prefix":"10.1002","volume":"33","author":[{"given":"Mozhgan","family":"Arabi","sequence":"first","affiliation":[{"name":"Department of Physics, Faculty of Science Vali\u2010e\u2010Asr University  Rafsanjan Iran"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8948-8465","authenticated-orcid":false,"given":"Seyyed Mahdy","family":"Baizaee","sequence":"additional","affiliation":[{"name":"Department of Physics, Faculty of Science Vali\u2010e\u2010Asr University  Rafsanjan Iran"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Alireza","family":"Bahador","sequence":"additional","affiliation":[{"name":"Department of Physics, Faculty of Science Vali\u2010e\u2010Asr University  Rafsanjan Iran"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Seyed Mohammad Taheri","family":"Otaqsara","sequence":"additional","affiliation":[{"name":"Department of Physics Shahed University  Tehran Iran"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2017,12,28]]},"reference":[{"volume-title":"Metal oxide nanoparticles","year":"2013","author":"Corr S. 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