{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,18]],"date-time":"2026-10-18T03:59:12Z","timestamp":1792295952652,"version":"4.4.0"},"reference-count":56,"publisher":"Wiley","issue":"3","license":[{"start":{"date-parts":[[2021,1,6]],"date-time":"2021-01-06T00:00:00Z","timestamp":1609891200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001501","name":"University Grants Commission","doi-asserted-by":"publisher","award":["F.540\/17\/DRS\u2010I\/2016 SAP\u2010I"],"award-info":[{"award-number":["F.540\/17\/DRS\u2010I\/2016 SAP\u2010I"]}],"id":[{"id":"10.13039\/501100001501","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["analyticalsciencejournals.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Luminescence"],"published-print":{"date-parts":[[2021,5]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>An efficient and cost\u2010effective technique, solution precipitation approach is adopted to synthesize five bright green luminescent terbium (III) complexes by employing the main \u03b2\u2010hydroxy ketone ligand, 2\u2010hydroxy\u20104\u2010ethoxyacetophenone, and ancillary ligands like bathophenanthroline, 5,6\u2010dimethyl\u20101,10\u2010phenanthroline, 1,10\u2010phenanthroline, and 2,2\u2010bipyridyl. The elemental compositions and binding mode of ligand to terbium (III) ion can be validated by using energy dispersive X\u2010ray analysis, elemental analysis, Fourier transform infrared, and proton nuclear magnetic resonance spectroscopy. The complexes are thermally stable up to 158\u00b0C and possess the cubic shaped particles as confirmed by thermogravimetric analysis and scanning electron microscopic study, respectively. The band\u2010gap energy (3.02\u20132.92 eV) of complexes is reckoned through diffuse reflectance spectra, which tailors them as potential candidates in the field of military radars. The photoluminescence studies unveil that the complexes exhibit the bright green luminescence corresponding to <jats:sup>5<\/jats:sup>D<jats:sub>4<\/jats:sub> \u2192 <jats:sup>7<\/jats:sup>F<jats:sub>5<\/jats:sub> transition of Tb<jats:sup>3+<\/jats:sup> ion (548 nm) under the excitation wavelength of 395 or 397 nm. The Commission International de I\u2019Eclairage chromaticity coordinates (x, y) and color purity substantiates the green emission of complexes. The energy transfer mechanism elucidates that the main ligand and ancillary ligands sensitize Tb<jats:sup>3+<\/jats:sup> ion, which in turn enhances the luminescence efficiency of the emissive layer of white organic light emitting diodes. The results reveal that the complexes are considered as good contenders in the field of display devices and laser technology. Lastly, <jats:italic>in vitro<\/jats:italic> antimicrobial and antioxidant activity proclaim the potent antimicrobial and antioxidant actions of complexes via tube dilution and 2, 2\u2010diphenyl\u20101\u2010picrylhydrazyl assays, respectively.<\/jats:p>","DOI":"10.1002\/bio.3998","type":"journal-article","created":{"date-parts":[[2020,12,19]],"date-time":"2020-12-19T17:20:01Z","timestamp":1608398401000},"page":"742-754","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":20,"title":["Photoluminescence performance of green light emitting terbium (III) complexes with \u03b2\u2010hydroxy ketone and nitrogen donor ancillary ligands"],"prefix":"10.1002","volume":"36","author":[{"given":"Jyoti","family":"Khanagwal","sequence":"first","affiliation":[{"name":"Department of Chemistry Maharshi Dayanand University  Rohtak India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rajesh","family":"Kumar","sequence":"additional","affiliation":[{"name":"University Institute of Engineering and Technology (UIET) Maharshi Dayanand University  Rohtak India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rekha","family":"Devi","sequence":"additional","affiliation":[{"name":"Department of Chemistry Maharshi Dayanand University  Rohtak India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Manju","family":"Bala","sequence":"additional","affiliation":[{"name":"Department of Chemistry Maharshi Dayanand University  Rohtak India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Priyanka","family":"Sehrawat","sequence":"additional","affiliation":[{"name":"Department of Chemistry Maharshi Dayanand University  Rohtak India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"S. P.","family":"Khatkar","sequence":"additional","affiliation":[{"name":"Department of Chemistry Maharshi Dayanand University  Rohtak India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3068-2455","authenticated-orcid":false,"given":"V. B.","family":"Taxak","sequence":"additional","affiliation":[{"name":"Department of Chemistry Maharshi Dayanand University  Rohtak India"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2021,1,6]]},"reference":[{"key":"e_1_2_9_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cplett.2020.138004"},{"key":"e_1_2_9_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/adom.201800538"},{"key":"e_1_2_9_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cplett.2020.137937"},{"key":"e_1_2_9_5_1","doi-asserted-by":"publisher","DOI":"10.1007\/s11431-017-9212-7"},{"key":"e_1_2_9_6_1","doi-asserted-by":"publisher","DOI":"10.1002\/bio.3777"},{"key":"e_1_2_9_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ceramint.2020.03.184"},{"key":"e_1_2_9_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b02792"},{"key":"e_1_2_9_9_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8TC06610H"},{"key":"e_1_2_9_10_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0TC01197E"},{"key":"e_1_2_9_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.snb.2018.06.128"},{"key":"e_1_2_9_12_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5DT02186C"},{"key":"e_1_2_9_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jssc.2019.01.007"},{"key":"e_1_2_9_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic401191e"},{"key":"e_1_2_9_15_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.matchemphys.2011.09.028"},{"key":"e_1_2_9_16_1","doi-asserted-by":"publisher","DOI":"10.1080\/00387010.2020.1817093"},{"key":"e_1_2_9_17_1","doi-asserted-by":"publisher","DOI":"10.1007\/s12034-016-1174-2"},{"key":"e_1_2_9_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/aoc.944"},{"key":"e_1_2_9_19_1","doi-asserted-by":"publisher","DOI":"10.1007\/s10854-019-02633-x"},{"key":"e_1_2_9_20_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.orgel.2009.04.023"},{"issue":"1","key":"e_1_2_9_21_1","first-page":"28","volume":"45","author":"Kumar R.","year":"2017","journal-title":"Int. J. Pharm. Sci. Rev. Res."},{"key":"e_1_2_9_22_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jopr.2012.11.037"},{"key":"e_1_2_9_23_1","doi-asserted-by":"publisher","DOI":"10.1007\/s10895-018-2239-y"},{"key":"e_1_2_9_24_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ica.2017.11.006"},{"key":"e_1_2_9_25_1","doi-asserted-by":"publisher","DOI":"10.1016\/S1002-0721(10)60534-0"},{"key":"e_1_2_9_26_1","doi-asserted-by":"publisher","DOI":"10.1007\/s10854-020-03160-w"},{"key":"e_1_2_9_27_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ceramint.2019.05.064"},{"key":"e_1_2_9_28_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.optmat.2016.03.041"},{"key":"e_1_2_9_29_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ceramint.2019.08.118"},{"key":"e_1_2_9_30_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cplett.2020.137758"},{"key":"e_1_2_9_31_1","doi-asserted-by":"publisher","DOI":"10.1039\/b909690f"},{"key":"e_1_2_9_32_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41598-019-45000-w"},{"key":"e_1_2_9_33_1","doi-asserted-by":"publisher","DOI":"10.1002\/bio.3800"},{"key":"e_1_2_9_34_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ijleo.2019.163636"},{"key":"e_1_2_9_35_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jlumin.2013.07.034"},{"key":"e_1_2_9_36_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ica.2010.09.003"},{"key":"e_1_2_9_37_1","doi-asserted-by":"publisher","DOI":"10.1080\/00387010.2020.1736099"},{"key":"e_1_2_9_38_1","first-page":"012024","volume":"436","author":"Wang Y.","year":"2018","journal-title":"Mater. Sci. Eng., A"},{"key":"e_1_2_9_39_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7RA01007A"},{"key":"e_1_2_9_40_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jlumin.2019.116697"},{"key":"e_1_2_9_41_1","volume-title":"Encyclopedia of color Science and Technology","author":"Schanda J.","year":"2015"},{"key":"e_1_2_9_42_1","doi-asserted-by":"publisher","DOI":"10.1002\/bio.3763"},{"key":"e_1_2_9_43_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jlumin.2018.10.031"},{"key":"e_1_2_9_44_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.snb.2016.12.080"},{"key":"e_1_2_9_45_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jallcom.2020.153641"},{"key":"e_1_2_9_46_1","doi-asserted-by":"publisher","DOI":"10.1007\/s10895-017-2069-3"},{"key":"e_1_2_9_47_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ceramint.2018.09.215"},{"key":"e_1_2_9_48_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.inoche.2011.06.025"},{"key":"e_1_2_9_49_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.heliyon.2019.e01687"},{"key":"e_1_2_9_50_1","doi-asserted-by":"publisher","DOI":"10.1080\/07391102.2015.1038585"},{"key":"e_1_2_9_51_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.tca.2013.07.020"},{"key":"e_1_2_9_52_1","doi-asserted-by":"publisher","DOI":"10.1016\/S1002-0721(16)60125-4"},{"key":"e_1_2_9_53_1","first-page":"1568","volume":"2","author":"Kumar S. M.","year":"2011","journal-title":"Int. J. Res. Pharmaceut. Biomed. Sci."},{"key":"e_1_2_9_54_1","first-page":"17","volume":"3","author":"Mondal P.","year":"2010","journal-title":"Trans. Pharm. Res."},{"key":"e_1_2_9_55_1","doi-asserted-by":"publisher","DOI":"10.1007\/s10895-007-0288-8"},{"key":"e_1_2_9_56_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00142a004"},{"key":"e_1_2_9_57_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-2313(97)00113-0"}],"container-title":["Luminescence"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/bio.3998","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/bio.3998","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/analyticalsciencejournals.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/bio.3998","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,8]],"date-time":"2025-10-08T14:28:31Z","timestamp":1759933711000},"score":1,"resource":{"primary":{"URL":"https:\/\/analyticalsciencejournals.onlinelibrary.wiley.com\/doi\/10.1002\/bio.3998"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2021,1,6]]},"references-count":56,"journal-issue":{"issue":"3","published-print":{"date-parts":[[2021,5]]}},"alternative-id":["10.1002\/bio.3998"],"URL":"https:\/\/doi.org\/10.1002\/bio.3998","archive":["Portico"],"relation":{},"ISSN":["1522-7235","1522-7243"],"issn-type":[{"value":"1522-7235","type":"print"},{"value":"1522-7243","type":"electronic"}],"subject":[],"published":{"date-parts":[[2021,1,6]]},"assertion":[{"value":"2020-10-15","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2020-12-17","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2021-01-06","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}]}}