{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,18]],"date-time":"2026-08-18T16:01:55Z","timestamp":1787068915213,"version":"build-2736575974"},"reference-count":37,"publisher":"Wiley","issue":"7","license":[{"start":{"date-parts":[[2021,7,21]],"date-time":"2021-07-21T00:00:00Z","timestamp":1626825600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001412","name":"Council of Scientific and Industrial Research, India","doi-asserted-by":"publisher","award":["09\/ 382(0207)\/2018\u2010EMR\u20101"],"award-info":[{"award-number":["09\/ 382(0207)\/2018\u2010EMR\u20101"]}],"id":[{"id":"10.13039\/501100001412","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["analyticalsciencejournals.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Luminescence"],"published-print":{"date-parts":[[2021,11]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    A green and highly efficient grinding method was adopted to synthesize emerald terbium complexes with 1\u2010cyclopropyl\u20106\u2010fluro\u20104\u2010oxo\u20107\u2010piperazin\u20101\u2010ylquinoline\u20103\u2010carboxylic acid as the main organic ligand and 2,2\u2032\u2010bipyridyl, 1,10\u2010phenanthroline, neocuproine, 5,6\u2010dimethyl\u20101,10\u2010phenanthroline and bathophenanthroline as ancillary ligands. Structural analysis of these complexes was executed via elemental, infrared and\n                    <jats:sup>1<\/jats:sup>\n                    H\u2010nuclear magnetic resonance analysis, which confirmed that the ligand coordinated to the metal ion through \u03b2\u2010ketone and hydroxyl groups of carboxylic acid. Thermal stability of these complexes was investigated by study of thermogravimetric\/derivative thermogravimetric analysis. Photoluminescence properties were investigated by observing emission spectra (400\u2013700\u2009nm), excitation spectra (250\u2013500\u2009nm) and decay time curves for display devices. The emission spectra revealed that an intense peak at 545\u2009nm was observed due to\n                    <jats:sup>5<\/jats:sup>\n                    D\n                    <jats:sub>4<\/jats:sub>\n                    \u2192\n                    <jats:sup>7<\/jats:sup>\n                    F\n                    <jats:sub>5<\/jats:sub>\n                    electronic transition, which is responsible for the emerald colour in synthesized complexes, under 353\u2009nm ultraviolet light excitation. The energy band gap and refractive index were determined, which proclaimed the dormant applications of these complexes in semiconductors. Commission Internationale de l'\u00e9clairage colour coordinates confirmed that the emerald emission of these complexes lies in the green region. Furthermore, antioxidant, antimicrobial and antimalarial assays of these complexes were also investigated, which confirmed that these complexes are potent for antioxidant, antimicrobial and antimalarial activities.\n                  <\/jats:p>","DOI":"10.1002\/bio.4106","type":"journal-article","created":{"date-parts":[[2021,6,19]],"date-time":"2021-06-19T07:45:48Z","timestamp":1624088748000},"page":"1658-1670","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":47,"title":["Designing of emerald terbium (III) ions with \u03b2\u2010ketocarboxylic acid and heterocyclic ancillary ligands for biological and optoelectronic applications"],"prefix":"10.1002","volume":"36","author":[{"given":"Pooja","family":"Hooda","sequence":"first","affiliation":[{"name":"Department of Chemistry Maharshi Dayanand University  Rohtak India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3068-2455","authenticated-orcid":false,"given":"Vinod Bala","family":"Taxak","sequence":"additional","affiliation":[{"name":"Department of Chemistry Maharshi Dayanand University  Rohtak India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6645-6877","authenticated-orcid":false,"given":"Rajesh Kumar","family":"Malik","sequence":"additional","affiliation":[{"name":"Department of Chemistry Maharshi Dayanand University  Rohtak India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Monika","family":"Punia","sequence":"additional","affiliation":[{"name":"Department of Chemistry Maharshi Dayanand University  Rohtak India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Pratibha","family":"Ahlawat","sequence":"additional","affiliation":[{"name":"University Institute of Engineering and Technology Maharshi Dayanand University  Rohtak India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Satyender Pal","family":"Khatkar","sequence":"additional","affiliation":[{"name":"Department of Chemistry Maharshi Dayanand University  Rohtak India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1070-9967","authenticated-orcid":false,"given":"Rajesh","family":"Kumar","sequence":"additional","affiliation":[{"name":"University Institute of Engineering and Technology Maharshi Dayanand University  Rohtak India"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2021,7,21]]},"reference":[{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6TC00579A"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr010309g"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/S1466-6049(01)00053-8"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jallcom.2016.06.040"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.dyepig.2016.12.059"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.displa.2010.02.007"},{"key":"e_1_2_7_8_1","first-page":"365","volume":"471","author":"Devi R.","year":"2017","journal-title":"Inorganica Chim. 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