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Their optical and electrochemical properties were investigated systematically. All these compounds exhibited intense absorption bands in the ultraviolet (UV) and visible regions, which arise from the \u03c0\u2013\u03c0* transitions based on their BODIPY core segments. By comparing electron\u2010withdrawing substituents and electron\u2010donating substituents, we found that these compounds exhibited some similar photophysical properties but exhibited different fluorescence in the solid state. All compounds were highly emissive in dichloromethane at room temperature (<jats:italic>\u03bb<\/jats:italic><jats:sub>em<\/jats:sub>\u2009=\u2009512\u2013523\u2009nm, <jats:italic>\u03a6<\/jats:italic><jats:sub>PL<\/jats:sub>\u2009&gt;\u20090.9). When these compounds were applied in blue\u2010driven light\u2010emitting diodes (LEDs) as light\u2010emitting materials, the devices showed luminescence efficiency ranging from 1.09 to 34.13\u2009lm\/W. Their luminescence and electrochemical properties could be used for understanding the structure\u2013property relationship of BODIPY compounds and developing functional fluorescent materials.<\/jats:p>","DOI":"10.1002\/bio.4111","type":"journal-article","created":{"date-parts":[[2021,6,22]],"date-time":"2021-06-22T20:35:26Z","timestamp":1624394126000},"page":"1697-1705","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":7,"title":["<i>Meso<\/i>\u2010substituted boron\u2010dipyrromethene compounds: synthesis, tunable solid\u2010state emission, and application in blue\u2010driven LEDs"],"prefix":"10.1002","volume":"36","author":[{"given":"Hao","family":"Liu","sequence":"first","affiliation":[{"name":"School of Chemistry and Molecular Engineering Nanjing Tech University  Nanjing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Huan","family":"Su","sequence":"additional","affiliation":[{"name":"School of 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