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Density functional theory (DFT) studies of tautomer compounds were done using (B3LYP) with a basis set of 6\u201031G(d,p). NLO analysis has shown that tautomer has mean first\u2010order hyperpolarisabilities (<jats:italic>\u03b2<\/jats:italic>) value of 1.8188\u2009\u00d7\u200910<jats:sup>\u221230<\/jats:sup>\u2009esu and 1.0470\u2009\u00d7\u200910<jats:sup>\u221230<\/jats:sup>\u00a0esu for azo and hydrazone forms, respectively, which is approximately nine and five times greater than the magnitude of urea. <jats:bold>4\u2010MCBA<\/jats:bold> exhibited two absorption peaks in the range of 290\u2013317 and 379\u2013394\u2009nm, and emission spectra were observed at 536\u2009nm. CV study demonstrated that the modified <jats:bold>4\u2010MCBA<\/jats:bold>\/MGC electrode exhibited excellent electrochemical sensitivity towards the detection of catechol and the detection limit is 9.39\u2009\u03bcM under optimum conditions. The <jats:bold>4\u2010MCBA<\/jats:bold> employed as a fluorescent probe for the visualisation of LFPs on various surfaces exhibited Level\u2010I to level\u2010II LFPs, with low background interference.<\/jats:p>","DOI":"10.1002\/bio.4825","type":"journal-article","created":{"date-parts":[[2024,7,4]],"date-time":"2024-07-04T03:25:45Z","timestamp":1720063545000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":8,"title":["Red\u2010emitting 4\u2010methyl coumarin fused barbituric acid as an electrochemical sensor for catechol detection and probe for latent fingerprints"],"prefix":"10.1002","volume":"39","author":[{"ORCID":"https:\/\/orcid.org\/0009-0007-9150-8297","authenticated-orcid":false,"given":"Surendranaik","family":"Yashyanaik","sequence":"first","affiliation":[{"name":"Department of P.G. 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