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In this work, a ZnO\u2013CuO composites were rationally designed and synthesized via a hydrothermal route and evaluated as a cataluminescence (CTL) sensing material for H\n                    <jats:sub>2<\/jats:sub>\n                    S monitoring. The sensor demonstrated a strong CTL response under mild operating conditions, offering a detection limit as low as 4\u2009ppm, rapid response, and recovery within 2.5\u2009s, and excellent selectivity against a broad panel of volatile organic and inorganic gases. Mechanistic investigations were conducted using BET surface analysis and energy band modeling based on the p\u2013n heterojunction structure to explore the origin of signal enhancement in the ZnO\u2013CuO composites. Validation with simulated gas mixtures confirmed good recovery and practical feasibility. These findings demonstrate the significant potential of ZnO\u2013CuO composites for selective, sensitive, and rapid H\n                    <jats:sub>2<\/jats:sub>\n                    S monitoring in the workplace.\n                  <\/jats:p>","DOI":"10.1002\/bio.70323","type":"journal-article","created":{"date-parts":[[2025,10,2]],"date-time":"2025-10-02T11:05:54Z","timestamp":1759403154000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Cataluminescence Sensor Based on ZnO\u2013CuO Composites for Rapid and Selective Detection of Hydrogen Sulfide"],"prefix":"10.1002","volume":"40","author":[{"given":"Quanquan","family":"Gong","sequence":"first","affiliation":[{"name":"Power Technology Center State Grid Shandong Electric Power Research Institute  Jinan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dandan","family":"Dou","sequence":"additional","affiliation":[{"name":"Power Technology Center State Grid Shandong Electric Power Research Institute  Jinan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guoying","family":"Zhang","sequence":"additional","affiliation":[{"name":"Power Technology Center State Grid Shandong Electric Power Research Institute  Jinan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kun","family":"Wang","sequence":"additional","affiliation":[{"name":"Power Technology Center State Grid Shandong Electric Power Research Institute  Jinan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jianguang","family":"Yin","sequence":"additional","affiliation":[{"name":"Power Technology Center State Grid Shandong Electric Power Research Institute  Jinan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiangyu","family":"Cui","sequence":"additional","affiliation":[{"name":"Power Technology Center State Grid Shandong Electric Power Research Institute  Jinan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0006-6162-0053","authenticated-orcid":false,"given":"Liuqian","family":"Yang","sequence":"additional","affiliation":[{"name":"Power Technology Center State Grid Shandong Electric Power Research Institute  Jinan China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,10,2]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jhazmat.2025.138389"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.3109\/10408444.2014.971943"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.snb.2008.10.043"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1039\/D5AN00382B"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1007\/s44211-022-00171-x"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.aca.2019.02.045"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.4c22780"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja207718t"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.3390\/molecules29143287"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/bio.70069"},{"key":"e_1_2_8_12_1","first-page":"32","article-title":"Application of Gas Detection Device Based on LoRa Wireless Communication in Electric Power Construction","volume":"3","author":"Gong W. 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