{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,25]],"date-time":"2025-10-25T21:45:46Z","timestamp":1761428746864,"version":"build-2065373602"},"reference-count":27,"publisher":"Wiley","issue":"1","license":[{"start":{"date-parts":[[2005,1,31]],"date-time":"2005-01-31T00:00:00Z","timestamp":1107129600000},"content-version":"vor","delay-in-days":30,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Luminescence"],"published-print":{"date-parts":[[2005,1]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Tetracyclines (TCs) were found to strongly inhibit the electrochemiluminescence (ECL) from the Ru(bpy)<jats:sub>3<\/jats:sub><jats:sup>2+<\/jats:sup>\u2013tripropylamine system when a working Pt electrode was maintained at 1.05 V (vs. Ag[sol ]AgCl) in pH 8.0 carbonate buffer solution. On this basis, a flow injection (FI) procedure with inhibited electrochemiluminescence detection has been developed for the determination of tetracycline (TC) and oxytetracycline (OTC). Under the optimized condition, the linear ranges of 2.0 \u00d7 10<jats:sup>\u22128<\/jats:sup>\u20131.0 \u00d7 10<jats:sup>\u22125<\/jats:sup> and 1.0 \u00d7 10<jats:sup>\u22128<\/jats:sup>\u20131.0 \u00d7 10<jats:sup>\u22125<\/jats:sup> g[sol ]mL and the detection limits of 4.0 \u00d7 10<jats:sup>\u22129<\/jats:sup> and 3.8 \u00d7 10<jats:sup>\u22129<\/jats:sup> g[sol ]mL were obtained for TC and OTC, respectively. The relative standard deviations (RSD) were 0.68% and 1.18% for 5.0 \u00d7 10<jats:sup>\u22127<\/jats:sup> g[sol ]mL TC and OTC (<jats:italic>n<\/jats:italic> = 13), respectively. The method showed higher sensitivity than most of the reported methods. It was successfully applied to the determination of tetracycline in a Chinese proprietary medicine, Tetracyclini and Cortisone Eye Ointment, and the residues of tetracycline in honey products. The inhibition mechanism has been proposed due to an energy transfer between electrogenerated Ru(bpy)<jats:sub>3<\/jats:sub><jats:sup>2+<\/jats:sup>* and benzoquinone derivatives at the electrode surface. Copyright \u00a9 2005 John Wiley &amp; Sons, Ltd.<\/jats:p>","DOI":"10.1002\/bio.793","type":"journal-article","created":{"date-parts":[[2005,1,31]],"date-time":"2005-01-31T11:48:12Z","timestamp":1107172092000},"page":"8-15","source":"Crossref","is-referenced-by-count":34,"title":["Flow injection analysis of tetracyclines using inhibited Ru(bpy)<sub>3<\/sub><sup>2+<\/sup>\/tripropylamine electrochemiluminescence system"],"prefix":"10.1002","volume":"20","author":[{"given":"Yong\u2010Qiang","family":"Pang","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Hua","family":"Cui","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Hai\u2010Song","family":"Zheng","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Guo\u2010Hui","family":"Wan","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Li\u2010Juan","family":"Liu","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Xiao\u2010Feng","family":"Yu","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2005,1,31]]},"reference":[{"key":"e_1_2_1_2_2","doi-asserted-by":"publisher","DOI":"10.1002\/bio.757"},{"volume-title":"Antibiotic Residues in Milk, Dairy Products and Animal Tissues: Methods, Reports and Protocols","year":"1968","key":"e_1_2_1_3_2"},{"key":"e_1_2_1_4_2","doi-asserted-by":"publisher","DOI":"10.1016\/0003-2670(83)80097-X"},{"key":"e_1_2_1_5_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0021-9673(01)90465-0"},{"key":"e_1_2_1_6_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0021-9673(00)82593-5"},{"key":"e_1_2_1_7_2","doi-asserted-by":"publisher","DOI":"10.1039\/an9891401141"},{"key":"e_1_2_1_8_2","doi-asserted-by":"publisher","DOI":"10.1016\/0039-9140(84)80281-7"},{"key":"e_1_2_1_9_2","doi-asserted-by":"publisher","DOI":"10.1039\/an9921701179"},{"key":"e_1_2_1_10_2","doi-asserted-by":"publisher","DOI":"10.1039\/an9911600183"},{"key":"e_1_2_1_11_2","doi-asserted-by":"publisher","DOI":"10.1016\/0039-9140(88)80030-4"},{"key":"e_1_2_1_12_2","doi-asserted-by":"publisher","DOI":"10.1080\/00032719008052487"},{"key":"e_1_2_1_13_2","doi-asserted-by":"publisher","DOI":"10.1039\/an9921701377"},{"key":"e_1_2_1_14_2","doi-asserted-by":"publisher","DOI":"10.1080\/00032719108053043"},{"key":"e_1_2_1_15_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.farmac.2003.09.002"},{"key":"e_1_2_1_16_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0003-2670(99)00668-6"},{"key":"e_1_2_1_17_2","doi-asserted-by":"publisher","DOI":"10.1016\/0003-2670(91)80075-5"},{"key":"e_1_2_1_18_2","doi-asserted-by":"publisher","DOI":"10.1007\/BF01243160"},{"key":"e_1_2_1_19_2","doi-asserted-by":"publisher","DOI":"10.1039\/an9941900879"},{"key":"e_1_2_1_20_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0039-9140(01)00312-5"},{"key":"e_1_2_1_21_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0003-2670(98)00545-5"},{"key":"e_1_2_1_22_2","doi-asserted-by":"publisher","DOI":"10.1007\/s00216-004-2519-z"},{"key":"e_1_2_1_23_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0003-2670(02)00930-3"},{"key":"e_1_2_1_24_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0039-9140(02)00576-3"},{"key":"e_1_2_1_25_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0003-2670(01)01590-2"},{"key":"e_1_2_1_26_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0003-2670(01)01050-9"},{"key":"e_1_2_1_27_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.aca.2003.10.035"},{"key":"e_1_2_1_28_2","doi-asserted-by":"publisher","DOI":"10.1039\/a904540f"}],"container-title":["Luminescence"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fbio.793","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/analyticalsciencejournals.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/bio.793","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,8]],"date-time":"2025-10-08T11:42:28Z","timestamp":1759923748000},"score":1,"resource":{"primary":{"URL":"https:\/\/analyticalsciencejournals.onlinelibrary.wiley.com\/doi\/10.1002\/bio.793"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2005,1]]},"references-count":27,"journal-issue":{"issue":"1","published-print":{"date-parts":[[2005,1]]}},"alternative-id":["10.1002\/bio.793"],"URL":"https:\/\/doi.org\/10.1002\/bio.793","archive":["Portico"],"relation":{},"ISSN":["1522-7235","1522-7243"],"issn-type":[{"type":"print","value":"1522-7235"},{"type":"electronic","value":"1522-7243"}],"subject":[],"published":{"date-parts":[[2005,1]]}}}