{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,3,17]],"date-time":"2026-03-17T18:15:10Z","timestamp":1773771310362,"version":"3.50.1"},"reference-count":32,"publisher":"Wiley","issue":"11","license":[{"start":{"date-parts":[[2010,11,5]],"date-time":"2010-11-05T00:00:00Z","timestamp":1288915200000},"content-version":"vor","delay-in-days":4,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Biotechnology Journal"],"published-print":{"date-parts":[[2010,11]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Bio\u2010ethanol dehydration to ethylene is an attractive alternative to oil\u2010based ethylene. The influence of fusel, main byproducts in the fermentation process of bio\u2010ethanol production, on the bio\u2010ethanol dehydration should not be ignored. We studied the catalytic dehydration of bio\u2010ethanol to ethylene over parent and modified HZSM\u20105 at 250\u00b0C, with weight hourly space velocity (WHSV) equal to 2.0\/h. The influences of a series of fusel, such as isopropanol, isobutanol and isopentanol, on the ethanol dehydration over the catalysts were investigated. The 0.5%La\u20102%PHZSM\u20105 catalyst exhibited higher ethanol conversion (100%), ethylene selectivity (99%), and especially enhanced stability (more than 70 h) than the parent and other modified HZSM\u20105. We demonstrated that the introduction of lanthanum and phosphorous to HZSM\u20105 could weaken the negative influence of fusel on the formation of ethylene. The physicochemical properties of the catalysts were characterized by ammonia temperature\u2010programmed desorption (NH<jats:sub>3<\/jats:sub>\u2010TPD), nitrogen adsorption and thermogravimetry (TG)\/differential thermogravimetry (DTG)\/differential thermal analysis (DTA) (TG\/DTG\/DTA) techniques. The results indicated that the introduction of lanthanum and phosphorous to HZSM\u20105 could inhibit the formation of coking during the ethanol dehydration to ethylene in the presence of fusel. The development of an efficient catalyst is one of the key technologies for the industrialization of bio\u2010ethylene.<\/jats:p>","DOI":"10.1002\/biot.201000139","type":"journal-article","created":{"date-parts":[[2010,11,7]],"date-time":"2010-11-07T09:59:57Z","timestamp":1289123997000},"page":"1186-1191","source":"Crossref","is-referenced-by-count":33,"title":["Selective dehydration of bio\u2010ethanol to ethylene catalyzed by lanthanum\u2010phosphorous\u2010modified HZSM\u20105: Influence of the fusel"],"prefix":"10.1002","volume":"5","author":[{"given":"Yaochi","family":"Hu","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Nina","family":"Zhan","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Chang","family":"Dou","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"He","family":"Huang","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yuwang","family":"Han","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Dinghua","family":"Yu","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yi","family":"Hu","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2010,11,5]]},"reference":[{"key":"e_1_2_1_2_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1137013"},{"key":"e_1_2_1_3_2","doi-asserted-by":"crossref","unstructured":"Huang H. Microbial ethanol its polymer polyethylene and applications in: Chen G. Q. (Ed.) Plastics from Bacteria: Natural Functions and Applications Springer Berlin 2010 pp. 389\u2013404.","DOI":"10.1007\/978-3-642-03287-5_15"},{"key":"e_1_2_1_4_2","doi-asserted-by":"publisher","DOI":"10.1080\/15583720902834791"},{"key":"e_1_2_1_5_2","doi-asserted-by":"publisher","DOI":"10.1002\/biot.200900150"},{"key":"e_1_2_1_6_2","doi-asserted-by":"publisher","DOI":"10.1002\/bbb.189"},{"key":"e_1_2_1_7_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.cattod.2007.01.071"},{"key":"e_1_2_1_8_2","doi-asserted-by":"publisher","DOI":"10.1088\/0957-4484\/20\/21\/215604"},{"key":"e_1_2_1_9_2","first-page":"6","article-title":"Development progress and industrialization of bio\u2010ethylene.","volume":"29","author":"Hu Y.","year":"2009","journal-title":"Mod. Chem. Ind."},{"key":"e_1_2_1_10_2","doi-asserted-by":"publisher","DOI":"10.1021\/ie9702542"},{"key":"e_1_2_1_11_2","doi-asserted-by":"publisher","DOI":"10.1007\/s10562-009-0047-3"},{"key":"e_1_2_1_12_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.micromeso.2008.04.004"},{"key":"e_1_2_1_13_2","unstructured":"Jacobs J. M. Jacobs P. A. Uytterhoeven J. B. Process for obtaining ethylene from ethanol. US patent: 4670620 1987."},{"key":"e_1_2_1_14_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0926-860X(96)00240-2"},{"key":"e_1_2_1_15_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2009.06.001"},{"key":"e_1_2_1_16_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.cattod.2004.04.051"},{"key":"e_1_2_1_17_2","doi-asserted-by":"publisher","DOI":"10.1021\/ie901666f"},{"key":"e_1_2_1_18_2","doi-asserted-by":"publisher","DOI":"10.1006\/jcat.1996.0191"},{"key":"e_1_2_1_19_2","unstructured":"Huang H. Zeng B. W. Su G. D. Li H.et al. A new technology for ethanol dehydration to ethylene. CA Patent: ZL 2007 1 0133610.9 2010."},{"key":"e_1_2_1_20_2","first-page":"1","article-title":"Isopropyl alcohol dehydration over chrominophosphate catalysts\u2010II. Deactivation.","volume":"31","author":"Kuo Y. C.","year":"2000","journal-title":"J. Chin. Inst. Chem. Eng."},{"key":"e_1_2_1_21_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2008.12.009"},{"key":"e_1_2_1_22_2","doi-asserted-by":"publisher","DOI":"10.1134\/S0023158410010234"},{"key":"e_1_2_1_23_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.catcom.2010.01.011"},{"key":"e_1_2_1_24_2","doi-asserted-by":"publisher","DOI":"10.1016\/S1002-0721(09)60205-2"},{"key":"e_1_2_1_25_2","unstructured":"Chen S. Y. Sun Y. H. Ding Y. J. Zhou R. X.et al.(Eds.) Adsorption and Catalysis Henan Science and Technology Press Zhengzhou 2001."},{"key":"e_1_2_1_26_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.catcom.2009.02.019"},{"key":"e_1_2_1_27_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0167-2991(09)60257-3"},{"key":"e_1_2_1_28_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.catcom.2003.11.008"},{"key":"e_1_2_1_29_2","unstructured":"Jia S. B. Li C. X. Wu G. F. (Eds.) New alcohol processing technology Chemical Industry Press Beijing 2004."},{"key":"e_1_2_1_30_2","doi-asserted-by":"publisher","DOI":"10.1007\/s10562-008-9481-x"},{"key":"e_1_2_1_31_2","doi-asserted-by":"publisher","DOI":"10.1016\/0021-9517(89)90217-0"},{"key":"e_1_2_1_32_2","doi-asserted-by":"publisher","DOI":"10.1016\/0304-5102(90)85224-6"},{"key":"e_1_2_1_33_2","first-page":"85","article-title":"Reactions of ethanol over HZSM\u20105.","volume":"110","author":"Szchnyi A.","year":"2006","journal-title":"Catal. Lett."}],"container-title":["Biotechnology Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fbiot.201000139","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/analyticalsciencejournals.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/biot.201000139","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,8]],"date-time":"2025-10-08T19:01:53Z","timestamp":1759950113000},"score":1,"resource":{"primary":{"URL":"https:\/\/analyticalsciencejournals.onlinelibrary.wiley.com\/doi\/10.1002\/biot.201000139"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2010,11]]},"references-count":32,"journal-issue":{"issue":"11","published-print":{"date-parts":[[2010,11]]}},"alternative-id":["10.1002\/biot.201000139"],"URL":"https:\/\/doi.org\/10.1002\/biot.201000139","archive":["Portico"],"relation":{},"ISSN":["1860-6768","1860-7314"],"issn-type":[{"value":"1860-6768","type":"print"},{"value":"1860-7314","type":"electronic"}],"subject":[],"published":{"date-parts":[[2010,11]]}}}