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L. (Primulaceae). For the very first time in a sample of natural origin, the presence of <jats:italic>iso<\/jats:italic>\u2010 and <jats:italic>anteiso<\/jats:italic>\u2010VLC FABEs and 2\u2010alkanones was unequivocally confirmed by synthetic work, derivatization, and NMR. It should be noted that the studied species produced unusually high amounts of branched wax constituents (e.\u2009g., &gt;50\u2009% of 2\u2010alkanones were branched isomers). The domination of <jats:italic>iso<\/jats:italic>\u2010isomers, probably biosynthesized from leucine\u2010derived starters, is a unique feature in the Plant Kingdom. The plant organ distribution of these VLC compounds in <jats:italic>P. acaulis<\/jats:italic> samples (different habitats and phenological phases) pointed to their possible ecological value. This was supported by a eutectic behavior of binary blends of FABEs and alkanes, as well as by high UV\u2010C absorption by FABEs.<\/jats:p>","DOI":"10.1002\/cbdv.202100285","type":"journal-article","created":{"date-parts":[[2021,5,24]],"date-time":"2021-05-24T11:54:56Z","timestamp":1621857296000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Very\u2010Long\u2010Chain Wax Constituents from <i>Primula veris<\/i> and <i>P. acaulis<\/i>: Does the Paradigm of Non\u2010Branched <i>vs<\/i>. Branched Chain Dominance Universally Hold in all Plant Taxa?"],"prefix":"10.1002","volume":"18","author":[{"given":"Milena Z.","family":"\u017divkovi\u0107 Sto\u0161i\u0107","sequence":"first","affiliation":[{"name":"Department of Chemistry Faculty of Sciences and Mathematics University of Ni\u0161  Vi\u0161egradska 33 18000 Ni\u0161 Serbia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1342-7567","authenticated-orcid":false,"given":"Niko S.","family":"Radulovi\u0107","sequence":"additional","affiliation":[{"name":"Department of Chemistry Faculty of Sciences and Mathematics University of Ni\u0161  Vi\u0161egradska 33 18000 Ni\u0161 Serbia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Marija S.","family":"Gen\u010di\u0107","sequence":"additional","affiliation":[{"name":"Department of Chemistry Faculty of Sciences and Mathematics University of Ni\u0161  Vi\u0161egradska 33 18000 Ni\u0161 Serbia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Vladimir N.","family":"Ran\u0111elovi\u0107","sequence":"additional","affiliation":[{"name":"Department of Biology and Ecology Faculty of Sciences and Mathematics University of Ni\u0161  Vi\u0161egradska 33 18000 Ni\u0161 Serbia"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2021,6,8]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.phytochem.2021.112732"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/cbdv.201900153"},{"key":"e_1_2_7_3_1","doi-asserted-by":"crossref","unstructured":"R. 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