{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,7]],"date-time":"2026-10-07T15:33:22Z","timestamp":1791387202771,"version":"4.3.3"},"reference-count":41,"publisher":"Wiley","issue":"3","license":[{"start":{"date-parts":[[2022,2,9]],"date-time":"2022-02-09T00:00:00Z","timestamp":1644364800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100004207","name":"Osmania University","doi-asserted-by":"publisher","award":["SB\/EMEQ-141\/2014"],"award-info":[{"award-number":["SB\/EMEQ-141\/2014"]}],"id":[{"id":"10.13039\/501100004207","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100018087","name":"Department of Chemistry, University of York","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100018087","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry &amp; Biodiversity"],"published-print":{"date-parts":[[2022,3]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Three metal complexes [Cu(FMIMDIP)\n                    <jats:sub>2<\/jats:sub>\n                    ] (\n                    <jats:bold>1<\/jats:bold>\n                    ), [Ni(FMIMDIP)\n                    <jats:sub>2<\/jats:sub>\n                    ] (\n                    <jats:bold>2<\/jats:bold>\n                    ) and [Co(FMIMDIP)\n                    <jats:sub>3<\/jats:sub>\n                    ] (\n                    <jats:bold>3<\/jats:bold>\n                    ) where, FMIMDIP=(((furan\u20102\u2010yl)methylimino)methyl)\u20104,6\u2010diiodophenol, were synthesized and characterized by various spectroscopy. The analytical data revealed a square planar geometry for\n                    <jats:bold>1<\/jats:bold>\n                    and\n                    <jats:bold>2<\/jats:bold>\n                    and an octahedral geometry for\n                    <jats:bold>3<\/jats:bold>\n                    . The kinetic and thermodynamic parameters of the thermal decomposition steps were calculated from the thermograms. The quantum chemical parameters have been calculated using HOMO\u2010LUMO energies and reveal the stability of the complexes. The DNA interaction of\n                    <jats:bold>1<\/jats:bold>\n                    \u2013\n                    <jats:bold>3<\/jats:bold>\n                    towards calf\u2010thymus DNA was investigated by absorption titration, fluorescence spectroscopy and gel electrophoresis. All the complexes bind to DNA via intercalation mode with binding constant (K\n                    <jats:sub>b<\/jats:sub>\n                    ) values of 4.17\u00d710\n                    <jats:sup>3<\/jats:sup>\n                    \u2005M\n                    <jats:sup>\u22121<\/jats:sup>\n                    to 5.9\u00d710\n                    <jats:sup>4<\/jats:sup>\n                    \u2005M\n                    <jats:sup>\u22121<\/jats:sup>\n                    and also effectively cleave pBR322 DNA by oxidative and photolytic techniques. The synergistic action of metal chelates with ascorbic acid induced the generation of free radicals. The antibacterial activity of\n                    <jats:bold>1<\/jats:bold>\n                    \u2013\n                    <jats:bold>3<\/jats:bold>\n                    was tested against\n                    <jats:italic>B.\u2005thuringiensis<\/jats:italic>\n                    ,\n                    <jats:italic>S.\u2005pneumoniae<\/jats:italic>\n                    ,\n                    <jats:italic>E.\u2005coli<\/jats:italic>\n                    , and\n                    <jats:italic>P.\u2005putida<\/jats:italic>\n                    . Complex\n                    <jats:bold>3<\/jats:bold>\n                    has the best activity among all the complexes.\n                  <\/jats:p>","DOI":"10.1002\/cbdv.202100686","type":"journal-article","created":{"date-parts":[[2022,2,9]],"date-time":"2022-02-09T05:02:10Z","timestamp":1644382930000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":15,"title":["A Treatise on Furan Cored Schiff Base Cu(II), Ni(II) and Co(III) Complexes Accentuating Their Biological Efficacy: Synthesis, Thermal and Spectroscopic Characterization, DNA Interactions, Antioxidant and Antibacterial Activity Studies"],"prefix":"10.1002","volume":"19","author":[{"given":"Kadtala","family":"Venkateswarlu","sequence":"first","affiliation":[{"name":"Department of Chemistry Osmania University  Hyderabad Telangana 500007 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Aveli","family":"Rambabu","sequence":"additional","affiliation":[{"name":"Department of Science and Humanities St. Martin's Engineering College, Dhulapally  Hyderabad Telangana 500100 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dasari Shiva","family":"Shankar","sequence":"additional","affiliation":[{"name":"Department of Chemistry Osmania University  Hyderabad Telangana 500007 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"P. V. Anantha","family":"Lakshmi","sequence":"additional","affiliation":[{"name":"Department of Chemistry Osmania University  Hyderabad Telangana 500007 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"family":"Shivaraj","sequence":"additional","affiliation":[{"name":"Department of Chemistry Osmania University  Hyderabad Telangana 500007 India"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2022,2,9]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.msec.2017.11.004"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.saa.2014.09.015"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.molstruc.2020.129356"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.molstruc.2019.127338"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/aoc.6326"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/0006-2952(90)90065-S"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jinorgbio.2020.111019"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ica.2020.119674"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.msec.2017.02.171"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ijbiomac.2020.06.278"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.msec.2018.04.032"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jinorgbio.2019.110902"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ica.2018.12.046"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.saa.2005.05.037"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0162-0134(03)00237-X"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.molstruc.2018.02.004"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.poly.2019.06.048"},{"key":"e_1_2_7_18_1","first-page":"30","article-title":"\u2018Molecular docking, DNA interaction and in\u2005vitro anti-cancer studies of square-planar Ni (II) and Cu (II) complexes\u2019","volume":"17","author":"Reddy P. R.","year":"2018","journal-title":"Chem. Data Coll."},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.poly.2006.09.091"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ejmech.2009.07.028"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.molstruc.2020.127988"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/aoc.5133"},{"key":"e_1_2_7_23_1","first-page":"e6530","article-title":"\u2018Synthesis, spectroscopic and thermal studies of Cu+2, Ni+2 and Co+3 complexes of Schiff base containing furan moiety. Antitumor, antioxidant, antibacterial and DNA interaction studies\u2019","volume":"35","author":"Venkateswarlu K.","year":"2021","journal-title":"Appl. Organomet. Chem."},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cdc.2020.100439"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1038\/201068a0"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.molliq.2016.02.072"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jorganchem.2020.121219"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ijbiomac.2010.12.001"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.inoche.2020.108247"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9NJ05913J"},{"key":"e_1_2_7_31_1","first-page":"910","article-title":"\u2018Plant extracts with metal ions as potential antimicrobial agents\u2019","volume":"55","author":"Tweedy B. G.","year":"1964","journal-title":"Phytopathology"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.molstruc.2015.03.012"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.molstruc.2019.127006"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1021\/np0100845"},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.1038\/1811199a0"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1021\/bi00394a013"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.poly.2020.114559"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9NJ05712A"},{"key":"e_1_2_7_39_1","doi-asserted-by":"publisher","DOI":"10.1021\/bi00786a026"},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.saa.2018.07.050"},{"key":"e_1_2_7_41_1","doi-asserted-by":"publisher","DOI":"10.1093\/ajcp\/45.4_ts.493"}],"container-title":["Chemistry &amp; Biodiversity"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/cbdv.202100686","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/cbdv.202100686","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/cbdv.202100686","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,8,26]],"date-time":"2023-08-26T22:22:48Z","timestamp":1693088568000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/cbdv.202100686"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2022,2,9]]},"references-count":41,"journal-issue":{"issue":"3","published-print":{"date-parts":[[2022,3]]}},"alternative-id":["10.1002\/cbdv.202100686"],"URL":"https:\/\/doi.org\/10.1002\/cbdv.202100686","archive":["Portico"],"relation":{},"ISSN":["1612-1872","1612-1880"],"issn-type":[{"value":"1612-1872","type":"print"},{"value":"1612-1880","type":"electronic"}],"subject":[],"published":{"date-parts":[[2022,2,9]]},"assertion":[{"value":"2021-08-23","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2022-01-14","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2022-02-09","order":2,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202100686"}}