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The cold\u2010seep microbes are an emerging source of novel bioactive natural products. Four new ansa\u2010ring opened linear ansamycin analogues, named olimycins E\u2212H (<jats:bold>1<\/jats:bold>\u2013<jats:bold>4<\/jats:bold>) were isolated from the cold\u2010seep\u2010derived <jats:italic>Streptomyces olivaceus<\/jats:italic> OUCLQ19\u20103. 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