{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,23]],"date-time":"2026-08-23T16:18:25Z","timestamp":1787501905909,"version":"build-2736575974"},"reference-count":48,"publisher":"Wiley","issue":"5","license":[{"start":{"date-parts":[[2024,4,18]],"date-time":"2024-04-18T00:00:00Z","timestamp":1713398400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry &amp; Biodiversity"],"published-print":{"date-parts":[[2024,5]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    In this paper, a new tridentate Schiff base ligand (L) with nitrogen donor atoms and its cadmium(II) complexes with the general formula of CdLX\n                    <jats:sub>2<\/jats:sub>\n                    (X=Cl\n                    <jats:sup>\u2212<\/jats:sup>\n                    , Br\n                    <jats:sup>\u2212<\/jats:sup>\n                    , I\n                    <jats:sup>\u2212<\/jats:sup>\n                    , SCN\n                    <jats:sup>\u2212<\/jats:sup>\n                    , N\n                    <jats:sub>3<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    , NO\n                    <jats:sub>3<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    ) have been synthesized and characterized by physical and spectral (FT\/IR, UV\u2010Vis, Mass, and\n                    <jats:sup>1<\/jats:sup>\n                    H,\n                    <jats:sup>13<\/jats:sup>\n                    C NMR spectroscopies) methods. Also nano\u2010structured cadmium chloride and bromide complexes were synthesized by sonochemical method and then used to prepare nanostructured cadmium oxide confirmed by XRD and SEM techniques. Thermal behavior of the compounds was studied in the temperature range of 25 to 900\u2009\u00b0C under N\n                    <jats:sub>2<\/jats:sub>\n                    atmosphere at a heating rate of 20\u2009\u00b0C\/ min. Moreover, thermo\u2010kinetic activation parameters of thermal decomposition steps were calculated according to the Coats\u2010Redfern relationship. Antimicrobial activities of the synthesized compounds against two gram\u2010positive and two gram\u2010negative bacteria such as\n                    <jats:italic>Bacillus subtilis<\/jats:italic>\n                    ,\n                    <jats:italic>Staphylococcus aureus<\/jats:italic>\n                    ,\n                    <jats:italic>Escherichia coli<\/jats:italic>\n                    ,\n                    <jats:italic>Pseudomonas aeruginosa<\/jats:italic>\n                    , and two fungi of\n                    <jats:italic>Candida albicans<\/jats:italic>\n                    and\n                    <jats:italic>Aspergillus niger<\/jats:italic>\n                    were investigated by well diffusion method. SEM technique was used to monitor the morphological changes of the bacteria treated with the compounds. The 2,2\u2010Diphenyl\u20101\u2010picrylhydrazyl(DPPH) and the ferric reducing antioxidant power (FRAP) methods were used to evaluate the antioxidant ability of the ligand and its cadmium(II) complexes. In final, the cytotoxicity properties of the ligand and some cadmium(II) complexes against PC3 cancer cells were evaluated by MTT (3\u2010(4,5\u2010dimethylthiazol\u20102\u2010yl)\u20102,5\u2010diphenyl\u20102H\u2010tetrazolium bromide) bioassay and nitric oxide (NO) level measurement. The morphological changes of prostate cancer (PC3) cells due to treatment with the ligand and its complexes confirmed their anticancer effectiveness.\n                  <\/jats:p>","DOI":"10.1002\/cbdv.202301667","type":"journal-article","created":{"date-parts":[[2024,3,19]],"date-time":"2024-03-19T14:59:10Z","timestamp":1710860350000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["New\n                    <i>penta<\/i>\n                    \u2010Coordinated Cadmium(II) Complexes: Synthesis, Characterization, Thermal, Antimicrobial, Antioxidant and Cytotoxicity Properties"],"prefix":"10.1002","volume":"21","author":[{"ORCID":"https:\/\/orcid.org\/0009-0006-5830-4148","authenticated-orcid":false,"given":"M.","family":"Nejadmirfathi","sequence":"first","affiliation":[{"name":"Department of Chemistry Yasouj University  Yasouj 7591874831 Iran"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8897-4683","authenticated-orcid":false,"given":"M.","family":"Montazerozohori","sequence":"additional","affiliation":[{"name":"Department of Chemistry Yasouj University  Yasouj 7591874831 Iran"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0253-2003","authenticated-orcid":false,"given":"R.","family":"Naghiha","sequence":"additional","affiliation":[{"name":"Department of Animal Sciences Yasouj University  Yasouj 7591874831 Iran"},{"name":"Department of Pathobiology Faculty of Veterinary Medicine Shahid Chamran University of Ahvaz  Ahvaz Iran"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8470-8844","authenticated-orcid":false,"given":"E.","family":"Panahi Kokhdan","sequence":"additional","affiliation":[{"name":"Medicinal Plants Research Center Yasuj University of Medical Sciences  Yasuj Iran"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,4,18]]},"reference":[{"key":"e_1_2_9_1_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr0683616"},{"issue":"9","key":"e_1_2_9_2_1","first-page":"1254","volume":"3","author":"Tobriya S. K.","year":"2014","journal-title":"Int. J. Sci. Res."},{"issue":"1","key":"e_1_2_9_3_1","first-page":"185","volume":"10","author":"Ashraf M. A.","year":"2011","journal-title":"IPCBEE"},{"key":"e_1_2_9_4_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5DT02822A"},{"key":"e_1_2_9_5_1","doi-asserted-by":"publisher","DOI":"10.1081\/SIM-100105255"},{"key":"e_1_2_9_6_1","doi-asserted-by":"publisher","DOI":"10.1038\/srep11544"},{"key":"e_1_2_9_7_1","doi-asserted-by":"publisher","DOI":"10.5155\/eurjchem.9.1.22-29.1671"},{"key":"e_1_2_9_8_1","doi-asserted-by":"publisher","DOI":"10.1080\/15533174.2016.1218511"},{"key":"e_1_2_9_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.arabjc.2021.103308"},{"key":"e_1_2_9_10_1","doi-asserted-by":"publisher","DOI":"10.1007\/s12038-022-00262-x"},{"key":"e_1_2_9_11_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7RA08633D"},{"key":"e_1_2_9_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.molstruc.2020.129393"},{"key":"e_1_2_9_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.msec.2013.10.030"},{"key":"e_1_2_9_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ultsonch.2018.02.050"},{"key":"e_1_2_9_15_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.msec.2017.03.150"},{"key":"e_1_2_9_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/poc.4180"},{"key":"e_1_2_9_17_1","doi-asserted-by":"publisher","DOI":"10.1080\/00958970802162723"},{"issue":"1","key":"e_1_2_9_18_1","first-page":"1","volume":"2","author":"Irshad S.","year":"2012","journal-title":"Res. J. Biol."},{"key":"e_1_2_9_19_1","doi-asserted-by":"publisher","DOI":"10.5155\/eurjchem.2.4.480-484.353"},{"key":"e_1_2_9_20_1","doi-asserted-by":"publisher","DOI":"10.5897\/AJMR2017.8545"},{"key":"e_1_2_9_21_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jiec.2013.10.027"},{"issue":"2","key":"e_1_2_9_22_1","first-page":"63","volume":"3","author":"Mehdizadeh K. A.","year":"2014","journal-title":"Galen Med. J."},{"key":"e_1_2_9_23_1","doi-asserted-by":"publisher","DOI":"10.3390\/molecules14103964"},{"key":"e_1_2_9_24_1","first-page":"810","volume":"33","author":"Phipps S. M.","year":"2007","journal-title":"Pharm. Forum"},{"key":"e_1_2_9_25_1","doi-asserted-by":"publisher","DOI":"10.3390\/molecules14114476"},{"key":"e_1_2_9_26_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.canlet.2004.06.010"},{"key":"e_1_2_9_27_1","doi-asserted-by":"publisher","DOI":"10.3109\/21691401.2016.1161641"},{"key":"e_1_2_9_28_1","doi-asserted-by":"publisher","DOI":"10.1002\/cber.187901201117"},{"key":"e_1_2_9_29_1","doi-asserted-by":"publisher","DOI":"10.1111\/j.1582-4934.2010.01137.x"},{"key":"e_1_2_9_30_1","doi-asserted-by":"publisher","DOI":"10.4103\/pm.pm_432_16"},{"key":"e_1_2_9_31_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.molstruc.2017.05.073"},{"key":"e_1_2_9_32_1","doi-asserted-by":"publisher","DOI":"10.1002\/poc.3718"},{"key":"e_1_2_9_33_1","doi-asserted-by":"publisher","DOI":"10.1002\/aoc.6181"},{"key":"e_1_2_9_34_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ica.2020.119918"},{"key":"e_1_2_9_35_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.poly.2009.02.024"},{"key":"e_1_2_9_36_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ijbiomac.2020.02.245"},{"key":"e_1_2_9_37_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.saa.2009.04.005"},{"key":"e_1_2_9_38_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jscs.2021.101325"},{"key":"e_1_2_9_39_1","doi-asserted-by":"publisher","DOI":"10.1007\/BF01912460"},{"key":"e_1_2_9_40_1","doi-asserted-by":"publisher","DOI":"10.5155\/eurjchem.2.2.178-188.240"},{"key":"e_1_2_9_41_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.molstruc.2010.06.002"},{"key":"e_1_2_9_42_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ica.2015.01.029"},{"key":"e_1_2_9_43_1","doi-asserted-by":"publisher","DOI":"10.1093\/jac\/35.3.421"},{"key":"e_1_2_9_44_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41598-017-16180-0"},{"key":"e_1_2_9_45_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ica.2019.119186"},{"key":"e_1_2_9_46_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.niox.2008.04.014"},{"key":"e_1_2_9_47_1","doi-asserted-by":"publisher","DOI":"10.1158\/0008-5472.CAN-12-1260"},{"key":"e_1_2_9_48_1","doi-asserted-by":"publisher","DOI":"10.4103\/1735-5362.236833"}],"container-title":["Chemistry &amp; Biodiversity"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/cbdv.202301667","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,3,12]],"date-time":"2025-03-12T04:54:52Z","timestamp":1741755292000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/cbdv.202301667"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,4,18]]},"references-count":48,"journal-issue":{"issue":"5","published-print":{"date-parts":[[2024,5]]}},"alternative-id":["10.1002\/cbdv.202301667"],"URL":"https:\/\/doi.org\/10.1002\/cbdv.202301667","archive":["Portico"],"relation":{},"ISSN":["1612-1872","1612-1880"],"issn-type":[{"value":"1612-1872","type":"print"},{"value":"1612-1880","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024,4,18]]},"assertion":[{"value":"2023-10-23","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2024-03-13","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2024-04-18","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202301667"}}