{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,2,23]],"date-time":"2026-02-23T02:07:56Z","timestamp":1771812476311,"version":"3.50.1"},"reference-count":36,"publisher":"Wiley","issue":"6","license":[{"start":{"date-parts":[[2024,5,22]],"date-time":"2024-05-22T00:00:00Z","timestamp":1716336000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry &amp; Biodiversity"],"published-print":{"date-parts":[[2024,6]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>The sensing behavior of 2,5\u2010thienylene\u2010bridged tetrakis(2,6\u2010dichlorophenyl)\u2010[26]hexaphyrin (<jats:bold>2<\/jats:bold>) towards various metal ions and anions were investigated by UV\u2013vis and fluorescence spectroscopies. Using this strapped hexaphyrin (2), the molecular sensor displayed highly selective and sensitive colorimetric responses to Cu<jats:sup>2+<\/jats:sup> and Hg<jats:sup>2+<\/jats:sup> in MeOH\/THF. The spectral changes are distinctive enough in the visible region of the spectrum to enable naked\u2010eye detection. The detection limits of Cu<jats:sup>2+<\/jats:sup> and Hg<jats:sup>2+<\/jats:sup> using this chemo\u2010sensor in a mixed MeOH\/THF solution were 1.978 and 1.283\u2005\u03bcM, respectively, and 1.052\u2005\u03bcM for F<jats:sup>\u2212<\/jats:sup> in dichloromethane. Chemosensor 2,5\u2010thienylene strapped [26]hexaphyrin (<jats:bold>2<\/jats:bold>) shows absorption responses both a 1\u2009:\u20091 molecular ratio for <jats:bold>2<\/jats:bold> interacting with Cu<jats:sup>2+<\/jats:sup> and Hg<jats:sup>2+<\/jats:sup> and a 1\u2009:\u20092 ratio between <jats:bold>2<\/jats:bold> and F<jats:sup>\u2212<\/jats:sup> ions.<\/jats:p>","DOI":"10.1002\/cbdv.202301727","type":"journal-article","created":{"date-parts":[[2024,2,24]],"date-time":"2024-02-24T15:59:15Z","timestamp":1708790355000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["2,5\u2010Thienylene\u2010Strapped [26]Hexaphyrin as Multifunctional Chemosensor for Hg<sup>2+<\/sup>, Cu<sup>2+<\/sup>, and F<sup>\u2212<\/sup> Ions"],"prefix":"10.1002","volume":"21","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-9221-3083","authenticated-orcid":false,"given":"Bulti Abdisa","family":"Kerayu","sequence":"first","affiliation":[{"name":"Chemistry Department Ambo University  Ambo Ethiopia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8060-348X","authenticated-orcid":false,"given":"Chen\u2010Hsiung","family":"Hung","sequence":"additional","affiliation":[{"name":"Institute of Chemistry Academia Sinica  128 Academia Road, Section\u20052, Nankang Taipei 11529 Taiwan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Anil Kumar","family":"Vardhaman","sequence":"additional","affiliation":[{"name":"Institute of Chemistry Academia Sinica  128 Academia Road, Section\u20052, Nankang Taipei 11529 Taiwan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Tibebu Alemu","family":"Ayanie","sequence":"additional","affiliation":[{"name":"Chemistry Department Ambo University  Ambo Ethiopia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Busha Jima","family":"Geneti","sequence":"additional","affiliation":[{"name":"Chemistry Department Ambo University  Ambo Ethiopia"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2024,5,22]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.5b00099"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4CS00436A"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1039\/b910560n"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4CS00179F"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7CS00528H"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7CS00528H"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1149\/2.0381816jes"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2005.04.022"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6AY02416E"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/aoc.4688"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1039\/B714412A"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.201201242"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.6b00021"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.3390\/molecules23040867"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1039\/c0cc01004a"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.bmc.2013.08.037"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1039\/b907775h"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200602481"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8NJ00760H"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6RA03364D"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/open.201800027"},{"issue":"4","key":"e_1_2_7_22_1","first-page":"226","volume":"11","author":"Shi Y.","year":"2023","journal-title":"Chemo. 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