{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,23]],"date-time":"2026-08-23T16:31:05Z","timestamp":1787502665116,"version":"build-2736575974"},"reference-count":119,"publisher":"Wiley","issue":"12","license":[{"start":{"date-parts":[[2025,8,11]],"date-time":"2025-08-11T00:00:00Z","timestamp":1754870400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2025,8,11]],"date-time":"2025-08-11T00:00:00Z","timestamp":1754870400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry &amp; Biodiversity"],"published-print":{"date-parts":[[2025,12]]},"abstract":"ABSTRACT<\/jats:title>\n \n A series of novel zinc(II) complexes derived from a tetradentate N\n 2<\/jats:sub>\n O\n 2<\/jats:sub>\n \u2010Schiff base ligand were synthesized using zinc halide and pseudohalide salts with the general formula ZnLX\n 2<\/jats:sub>\n (X\u00a0=\u00a0Cl\n \u2212<\/jats:sup>\n , Br\n \u2212<\/jats:sup>\n , I\n \u2212<\/jats:sup>\n , N\n 3<\/jats:sub>\n \u2212<\/jats:sup>\n , SCN\n \u2212<\/jats:sup>\n ). The resulting compounds were thoroughly characterized by a range of spectroscopic and physicochemical techniques. Additionally, nanostructured zinc complexes such as ZnLBr\n 2<\/jats:sub>\n and ZnLI\n 2<\/jats:sub>\n were synthesized via an ultrasound\u2010assisted approach, with ZnLI\n 2<\/jats:sub>\n subsequently utilized as a precursor for the fabrication of ZnO nanoparticles. The nanostructures were confirmed by scanning electron microscopy (SEM), EDX, and x\u2010ray diffraction (XRD) analyses. Thermal decomposition studies of the ligand and its zinc complexes revealed two\u2010 to three\u2010step degradation processes, for which key thermokinetic parameters (\n E<\/jats:italic>\n *, \u0394\n S*<\/jats:italic>\n , \u0394\n H<\/jats:italic>\n *\n , A<\/jats:italic>\n , and \u0394\n G<\/jats:italic>\n *) were determined. From a biological standpoint, the synthesized compounds displayed potent antimicrobial activity against selected Gram\u2010positive (\n Staphylococcus aureus<\/jats:italic>\n and\n Bacillus subtilis<\/jats:italic>\n ) and Gram\u2010negative (\n Pseudomonas aeruginosa<\/jats:italic>\n and\n Escherichia coli<\/jats:italic>\n ) bacterial strains, as well as fungal pathogens (\n Aspergillus oryzae<\/jats:italic>\n and\n Candida albicans<\/jats:italic>\n ). DNA cleavage assays further confirmed the nucleolytic potential of these complexes. Selected compounds demonstrated noteworthy cytotoxic effects against the PC3 human prostate cancer cell line, substantiating their anticancer capabilities. Antioxidant properties were evaluated using DPPH (2,2\u2010diphenyl\u20101\u2010picrylhydrazyl) and FRAP (ferric reducing antioxidant power) assays, exhibiting promising radical\u2010scavenging activity. Notably, the ligand and ZnLI\n 2<\/jats:sub>\n complex also exhibited significant efficacy in promoting burn wound healing, highlighting their therapeutic potential in both infectious and regenerative medicine.\n <\/jats:p>","DOI":"10.1002\/cbdv.202500817","type":"journal-article","created":{"date-parts":[[2025,8,11]],"date-time":"2025-08-11T19:31:29Z","timestamp":1754940689000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Some New Zinc Halide Complexes of N\n 2<\/sub>\n O\n 2<\/sub>\n \u2010Schiff Base: Synthesis, Thermal, Antimicrobial, Antioxidant, Anticancer and Burn Wound Healing Effects"],"prefix":"10.1002","volume":"22","author":[{"ORCID":"https:\/\/orcid.org\/0009-0001-2681-6433","authenticated-orcid":false,"given":"Ameneh","family":"Malekhoseini","sequence":"first","affiliation":[{"name":"Department of Chemistry Yasouj University Yasuj Iran"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8897-4683","authenticated-orcid":false,"given":"Morteza","family":"Montazerozohori","sequence":"additional","affiliation":[{"name":"Department of Chemistry Yasouj University Yasuj Iran"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Reza","family":"Naghiha","sequence":"additional","affiliation":[{"name":"Department of Pathobiology, Faculty of Veterinary Medicine Shahid Chamran University of Ahvaz Ahvaz Iran"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Esmaeel Panahi","family":"Kokhdan","sequence":"additional","affiliation":[{"name":"Medicinal Plants Research Center Yasuj University of Medical Sciences Yasuj Iran"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shima","family":"Hosseinifar","sequence":"additional","affiliation":[{"name":"Department of Basic Sciences, Faculty of Veterinary Medicine Shahid Chamran University of Ahvaz Ahvaz Iran"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,8,11]]},"reference":[{"key":"e_1_2_8_2_1","first-page":"343","article-title":"Schiff Base Reaction. 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