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In this study, sulfonated carbon catalysts were synthesized from lavender biomass residue, obtained after essential oil extraction, through hydrothermal carbonization (HTC) followed by in situ sulfonation, and applied in the acetalization of glycerol with acetone to produce solketal, a bio\u2010based fuel additive. To the best of our knowledge, this type of residue has not yet been explored for this specific application. Characterization by XRD and Fourier\u2010transform infrared spectroscopy (FT\u2010IR) confirmed the amorphous carbon structure and successful incorporation of \u2500SO\n                    <jats:sub>3<\/jats:sub>\n                    H groups. The formation of solketal was confirmed by nuclear magnetic resonance (NMR) and gas chromatography\u2013mass spectrometry (GC\u2013MS). The catalyst exhibited excellent performance under mild conditions, achieving 97% glycerol conversion and 98% selectivity toward solketal. Optimal conditions (40\u00b0C, 30\u00a0min, 7.5 wt% catalyst loading, and a glycerol\u2010to\u2010acetone molar ratio of 1:20) afforded high glycerol conversion and selectivity toward solketal. The catalyst exhibited remarkable stability, maintaining &gt;96% conversion and &gt;97% selectivity after seven reuse cycles, confirming the potential of lavender waste as a sustainable precursor for catalyst development. These results highlight the potential of lavender agro\u2010residues as a sustainable carbon source for the production of efficient heterogeneous catalysts in renewable fuel applications.\n                  <\/jats:p>","DOI":"10.1002\/cbdv.71558","type":"journal-article","created":{"date-parts":[[2026,8,8]],"date-time":"2026-08-08T17:35:34Z","timestamp":1786210534000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Efficient Solketal Synthesis via Acetalization Using Sulfonated Carbon From Lavender Leaf Waste After Essential Oil Extraction"],"prefix":"10.1002","volume":"23","author":[{"ORCID":"https:\/\/orcid.org\/0009-0001-1755-3942","authenticated-orcid":false,"given":"Julianne A.","family":"Bruno","sequence":"first","affiliation":[{"name":"Department of Chemistry Federal University of Vi\u00e7osa  Vi\u00e7osa Minas Gerais Brazil"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guilherme R.","family":"Pereira","sequence":"additional","affiliation":[{"name":"Department of Chemistry Federal University of Vi\u00e7osa  Vi\u00e7osa Minas Gerais Brazil"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6673-3280","authenticated-orcid":false,"given":"Kelly R.","family":"Francisco","sequence":"additional","affiliation":[{"name":"Department of Natural Sciences Mathematics and Education Federal University of S\u00e3o Carlos  Araras S\u00e3o Paulo Brazil"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Gabriel H. M. de O.","family":"Pinto","sequence":"additional","affiliation":[{"name":"Department of Chemistry Federal University of Vi\u00e7osa  Vi\u00e7osa Minas Gerais Brazil"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Eraldo","family":"Lima","sequence":"additional","affiliation":[{"name":"Department of Entomology \u2010 BIOAGRO Federal University of Vi\u00e7osa  Vi\u00e7osa Minas Gerais Brazil"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ulisses A.","family":"Pereira","sequence":"additional","affiliation":[{"name":"Institute of Agricultural Sciences Federal University of Minas Gerais  Montes Claros Minas Gerais Brazil"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Garbas A. dos S.","family":"Junior","sequence":"additional","affiliation":[{"name":"Department of Chemistry Federal University of Vi\u00e7osa  Vi\u00e7osa Minas Gerais Brazil"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Patr\u00edcia F.","family":"Pinheiro","sequence":"additional","affiliation":[{"name":"Department of Chemistry Federal University of Vi\u00e7osa  Vi\u00e7osa Minas Gerais Brazil"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,8,8]]},"reference":[{"key":"e_1_2_9_2_1","doi-asserted-by":"publisher","DOI":"10.3390\/pr14020339"},{"key":"e_1_2_9_3_1","doi-asserted-by":"publisher","DOI":"10.3390\/su17041660"},{"key":"e_1_2_9_4_1","doi-asserted-by":"publisher","DOI":"10.3390\/plants12020357"},{"key":"e_1_2_9_5_1","volume-title":"Handbook of Essential Oils: Science, Technology, and Applications","author":"Ba\u015fer K. 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