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Here, we report the identification of the cyanohydrin of glyoxylic acid as the precursor of hydrocyanic acid in the fungus <jats:italic>Marasmius oreades<\/jats:italic> and several other cyanogenic fungi. Moreover, a feeding experiment revealed glycine as biosynthetic precursor of the cyanohydrin of glyoxylic acid. Thus, the cyanogenesis of <jats:italic>M. oreades<\/jats:italic> and other fungi is fundamentally different from cyanogenesis in plants.<\/jats:p>","DOI":"10.1002\/cbic.201402453","type":"journal-article","created":{"date-parts":[[2015,1,28]],"date-time":"2015-01-28T11:42:01Z","timestamp":1422445321000},"page":"570-573","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":20,"title":["A Free Cyanohydrin as Arms and Armour of <i>Marasmius oreades<\/i>"],"prefix":"10.1002","volume":"16","author":[{"given":"Jan","family":"Caspar","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Peter","family":"Spiteller","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2015,1,28]]},"reference":[{"key":"e_1_2_4_1_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200800292"},{"key":"e_1_2_4_2_2","unstructured":"\u00a0"},{"key":"e_1_2_4_3_2","doi-asserted-by":"publisher","DOI":"10.1104\/pp.94.2.401"},{"key":"e_1_2_4_4_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0041-0101(99)00128-2"},{"key":"e_1_2_4_5_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.phytochem.2008.02.019"},{"key":"e_1_2_4_6_2","doi-asserted-by":"publisher","DOI":"10.1002\/ardp.18711970104"},{"key":"e_1_2_4_7_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200702481"},{"key":"e_1_2_4_7_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200702481"},{"key":"e_1_2_4_8_2","unstructured":"\u00a0"},{"key":"e_1_2_4_9_2","first-page":"581","volume":"43","author":"Lebeau J. 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