{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,24]],"date-time":"2026-09-24T17:09:51Z","timestamp":1790269791261,"version":"4.1.0"},"reference-count":55,"publisher":"Wiley","issue":"7","license":[{"start":{"date-parts":[[2018,2,23]],"date-time":"2018-02-23T00:00:00Z","timestamp":1519344000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001659","name":"Deutsche Forschungsgemeinschaft","doi-asserted-by":"publisher","award":["PA 2395\/2-1"],"award-info":[{"award-number":["PA 2395\/2-1"]}],"id":[{"id":"10.13039\/501100001659","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemCatChem"],"published-print":{"date-parts":[[2018,4,9]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>An <jats:sup>17<\/jats:sup>O\u2005NMR spectroscopy survey of more than 100 ubiquitous organic solvents and compounds, including some typical oxofluorinated solvents such as hexafluoroisopropanol, trifluoroethanol, trifluoroacetic acid, and others, is presented with D<jats:sub>2<\/jats:sub>O as a reference. A strong alternating \u03b1,\u03b2\u2212CF<jats:sub>3<\/jats:sub>\u2010substituent chemical shift effect was thus observed. This alternating deshielding\u2013shielding effect is suspected to have a role in the exceptional properties of these oxofluorinated solvents, notably in oxidative cross\u2010coupling reactions.<\/jats:p>","DOI":"10.1002\/cctc.201701721","type":"journal-article","created":{"date-parts":[[2017,12,16]],"date-time":"2017-12-16T16:48:20Z","timestamp":1513442900000},"page":"1547-1551","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":18,"title":["The Strong \u03b2\u2212CF<sub>3<\/sub> Shielding Effect in Hexafluoroisopropanol and 100 Other Organic Solvents Revisited with <sup>17<\/sup>O\u2005NMR Spectroscopy"],"prefix":"10.1002","volume":"10","author":[{"given":"Annika","family":"Bernhardt","sequence":"first","affiliation":[{"name":"FB Chemie TU Kaiserslautern  Erwin Schr\u00f6dinger Strasse 52 67663 Kaiserslautern 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