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Here we show that few\u2010layer black phosphorous (FL\u2010BP), a recently discovered and now readily available 2D material, catalyzes different radical additions to alkenes with an initial turnover frequency (TOF<jats:sub>0<\/jats:sub>) up to two orders of magnitude higher than representative state\u2010of\u2010the\u2010art metal complex catalysts at room temperature. The corresponding electron\u2010rich BP intercalation compound (BPIC) KP<jats:sub>6<\/jats:sub> shows a nearly twice TOF<jats:sub>0<\/jats:sub> increase with respect to FL\u2010BP. This increase in catalytic activity respect to the neutral counterpart also occurs in other 2D materials (graphene vs. KC<jats:sub>8<\/jats:sub>) and metal complex catalysts (Fe<jats:sup>0<\/jats:sup> vs. Fe<jats:sup>2\u2212<\/jats:sup> carbon monoxide complexes). This reactive parallelism opens the door for cross\u2010fertilization between 2D materials and metal catalysts in organic synthesis.<\/jats:p>","DOI":"10.1002\/cctc.201902276","type":"journal-article","created":{"date-parts":[[2020,1,13]],"date-time":"2020-01-13T11:38:09Z","timestamp":1578915489000},"page":"2226-2232","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":18,"title":["Few\u2010layer Black Phosphorous Catalyzes Radical Additions to Alkenes Faster than Low\u2010valence Metals"],"prefix":"10.1002","volume":"12","author":[{"given":"Mar\u00eda","family":"Tejeda\u2010Serrano","sequence":"first","affiliation":[{"name":"Instituto de Tecnolog\u00eda Qu\u00edmica Universitat Polit\u00e8cnica de Val\u00e8ncia-Consejo Superior de Investigaciones Cient\u00edficas  Avda. de los Naranjos s\/n 46022 Valencia 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