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The adduct rearranges into two further adducts, one of which is characterised as a new type of fullerene derivative, a thiiranofullerene, formed by elimination of a thioketene moiety from the tetrathiafulvalene adduct. The initial addition also produces a bisadduct in which the addends comprise one tetrathiafulvalene molecule and one in which carbon disulfide has been eliminated. The latter adduct involves cycloaddition of an unsaturated aromatic dithiolactone moiety.<\/jats:p>","DOI":"10.1002\/chem.200204549","type":"journal-article","created":{"date-parts":[[2003,5,5]],"date-time":"2003-05-05T11:02:03Z","timestamp":1052132523000},"page":"2008-2012","source":"Crossref","is-referenced-by-count":16,"title":["Formation of Novel Sulfur\u2010Containing C<sub>60<\/sub>F<sub>16<\/sub> Cycloadducts between Tetrathiafulvalene and C<sub>60<\/sub>F<sub>18<\/sub>; A Unique Six\u2010Electron Cycloaddition of a Fullerene Involving F<sub>2<\/sub> Loss"],"prefix":"10.1002","volume":"9","author":[{"given":"Adam D.","family":"Darwish","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Anthony G.","family":"Avent","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Olga V.","family":"Boltalina","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ilya","family":"Gol\u2032dt","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Igor","family":"Kuvytchko","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Tatiana","family":"Da Ros","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Joan M.","family":"Street","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Roger","family":"Taylor","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2003,5,5]]},"reference":[{"key":"e_1_2_6_1_2","doi-asserted-by":"publisher","DOI":"10.1039\/a803737j"},{"key":"e_1_2_6_1_3","doi-asserted-by":"publisher","DOI":"10.1021\/jo991248d"},{"key":"e_1_2_6_1_4","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4039(00)01309-5"},{"key":"e_1_2_6_1_5","doi-asserted-by":"publisher","DOI":"10.1016\/S0379-6779(99)00199-X"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1039\/cc9960002549"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1039\/b002908o"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo9602231"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja0005744"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1039\/b208670k"}],"container-title":["Chemistry \u2013 A European Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fchem.200204549","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.200204549","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T09:06:23Z","timestamp":1760259983000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/chem.200204549"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2003,5,5]]},"references-count":9,"journal-issue":{"issue":"9","published-print":{"date-parts":[[2003,5,9]]}},"alternative-id":["10.1002\/chem.200204549"],"URL":"https:\/\/doi.org\/10.1002\/chem.200204549","archive":["Portico"],"relation":{},"ISSN":["0947-6539","1521-3765"],"issn-type":[{"type":"print","value":"0947-6539"},{"type":"electronic","value":"1521-3765"}],"subject":[],"published":{"date-parts":[[2003,5,5]]}}}