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Complex <jats:bold>1<\/jats:bold> exhibits a hydrogen\u2010bonded dimeric structure, <jats:bold>2<\/jats:bold> is a neutral monomeric complex, <jats:bold>3<\/jats:bold> has a trinuclear structure with the ophen ligand acting as a bridge through the ketone groups, and <jats:bold>4<\/jats:bold> features a tetranuclear Zn<jats:sub>4<\/jats:sub>O core that is consolidated further by bridging ophen and acetate ligands. All the complexes display photoluminescent properties in the blue\/green region. The photoluminescent mechanisms were investigated by means of molecular orbital calculations, which showed that the photoluminescent properties are ligand\u2010based and can be tuned upon ligation to different metal ions.<\/jats:p>","DOI":"10.1002\/chem.200304855","type":"journal-article","created":{"date-parts":[[2003,8,8]],"date-time":"2003-08-08T09:17:53Z","timestamp":1060334273000},"page":"3888-3896","source":"Crossref","is-referenced-by-count":111,"title":["Syntheses, Structures, Photoluminescence, and Theoretical Studies of a Novel Class of d<sup>10<\/sup> Metal Complexes of 1<i>H<\/i>\u2010[1,10]phenanthrolin\u20102\u2010one"],"prefix":"10.1002","volume":"9","author":[{"given":"Shao\u2010Liang","family":"Zheng","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jie\u2010Peng","family":"Zhang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiao\u2010Ming","family":"Chen","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhen\u2010Li","family":"Huang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhen\u2010Yang","family":"Lin","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wing\u2010Tak","family":"Wong","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2003,8,7]]},"reference":[{"key":"e_1_2_6_1_2","unstructured":"\u00a0"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0010-8545(98)90027-3"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0010-8545(00)00403-3"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.98799"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.343409"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1143\/JJAP.32.674"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1143\/JJAP.35.182"},{"key":"e_1_2_6_8_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-4095(199910)11:15<1266::AID-ADMA1266>3.0.CO;2-H"},{"key":"e_1_2_6_9_2","unstructured":"\u00a0"},{"key":"e_1_2_6_10_2","doi-asserted-by":"publisher","DOI":"10.1021\/om980199c"},{"key":"e_1_2_6_11_2","doi-asserted-by":"publisher","DOI":"10.1021\/om980536h"},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja9944249"},{"key":"e_1_2_6_13_2","unstructured":"\u00a0"},{"key":"e_1_2_6_14_2","doi-asserted-by":"publisher","DOI":"10.1039\/dt9930000467"},{"key":"e_1_2_6_15_2","first-page":"2491","author":"Ho K.\u2010Y.","year":"1998","journal-title":"Chem. 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