{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,1,20]],"date-time":"2026-01-20T09:53:04Z","timestamp":1768902784349,"version":"3.49.0"},"reference-count":150,"publisher":"Wiley","issue":"8","license":[{"start":{"date-parts":[[2005,2,1]],"date-time":"2005-02-01T00:00:00Z","timestamp":1107216000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2005,4,8]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Reaction of NH<jats:sub>4<\/jats:sub>VO<jats:sub>3<\/jats:sub> with sulfur dioxide affords the hexanuclear cluster (NH<jats:sub>4<\/jats:sub>)<jats:sub>2<\/jats:sub>(Et<jats:sub>4<\/jats:sub>N)[(V<jats:sup>IV<\/jats:sup>O)<jats:sub>6<\/jats:sub>(\u03bc<jats:sub>4<\/jats:sub>\u2010O)<jats:sub>2<\/jats:sub>(\u03bc<jats:sub>3<\/jats:sub>\u2010OH)<jats:sub>2<\/jats:sub>(\u03bc<jats:sub>3<\/jats:sub>\u2010SO<jats:sub>3<\/jats:sub>)<jats:sub>4<\/jats:sub>(H<jats:sub>2<\/jats:sub>O)<jats:sub>2<\/jats:sub>]Cl\u22c5H<jats:sub>2<\/jats:sub>O (<jats:bold>1<\/jats:bold>), and the decapentanuclear host\u2013guest compound (Et<jats:sub>4<\/jats:sub>N)<jats:sub>5<\/jats:sub>{Cl\u2282 [(VO)<jats:sub>15<\/jats:sub>(\u03bc<jats:sub>3<\/jats:sub>\u2010O)<jats:sub>18<\/jats:sub>(\u03bc\u2010O)<jats:sub>3<\/jats:sub>]}\u22c53\u2009H<jats:sub>2<\/jats:sub>O (<jats:bold>2<\/jats:bold>). Sequential addition of magnesium oxide to an acidic aqueous solution of NH<jats:sub>4<\/jats:sub>VO<jats:sub>3<\/jats:sub> (pH\u22480) followed by (NH<jats:sub>4<\/jats:sub>)<jats:sub>2<\/jats:sub>SO<jats:sub>3<\/jats:sub> resulted in the formation of either the non\u2010oxo polymeric vanadium(<jats:sc>IV<\/jats:sc>) compound <jats:italic>trans<\/jats:italic>\u2010(NH<jats:sub>4<\/jats:sub>)<jats:sub>2<\/jats:sub>[V<jats:sup>IV<\/jats:sup>(OH)<jats:sub>2<\/jats:sub>(\u03bc\u2010SO<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>] (<jats:bold>3<\/jats:bold>) or the polymeric oxovanadium(<jats:sc>IV<\/jats:sc>) sulfite (NH<jats:sub>4<\/jats:sub>)[V<jats:sup>IV<\/jats:sup>O(SO<jats:sub>3<\/jats:sub>)<jats:sub>1.5<\/jats:sub>(H<jats:sub>2<\/jats:sub>O)]\u22c52.5\u2009H<jats:sub>2<\/jats:sub>O (<jats:bold>4<\/jats:bold>) at pH values of 6 and 4, respectively. The decameric vanadium(<jats:sc>V<\/jats:sc>) compound {Na<jats:sub>4<\/jats:sub>(\u03bc\u2010H<jats:sub>2<\/jats:sub>O)<jats:sub>8<\/jats:sub>(H<jats:sub>2<\/jats:sub>O)<jats:sub>6<\/jats:sub>}[Mg(H<jats:sub>2<\/jats:sub>O)<jats:sub>6<\/jats:sub>][V<jats:styled-content>${{{{\\rm V}\\hfill \\atop 10\\hfill}}}$<jats:inline-graphic xmlns:xlink=\"http:\/\/www.w3.org\/1999\/xlink\" xlink:href=\"graphic\/tex2gif-ueqn-1.gif\" xlink:title=\"equation image\"\/><\/jats:styled-content>(O)<jats:sub>8<\/jats:sub>(\u03bc<jats:sub>6<\/jats:sub>\u2010O)<jats:sub>2<\/jats:sub>(\u03bc<jats:sub>3<\/jats:sub>\u2010O)<jats:sub>14<\/jats:sub>]\u22c53\u2009H<jats:sub>2<\/jats:sub>O (<jats:bold>5<\/jats:bold>) was synthesised by treating an acidic aqueous solution of NH<jats:sub>4<\/jats:sub>VO<jats:sub>3<\/jats:sub> with MgO and addition of NaOH to pH\u22486. All the compounds were characterised by single\u2010crystal X\u2010ray structure analysis. The crystal structure of compound <jats:bold>1<\/jats:bold> revealed an unprecedented structural motif of a cubane unit [M<jats:sub>4<\/jats:sub>(\u03bc<jats:sub>4<\/jats:sub>\u2010O)<jats:sub>2<\/jats:sub>(\u03bc<jats:sub>3<\/jats:sub>\u2010OH)<jats:sub>2<\/jats:sub>] connected to two other metal atoms. Compound <jats:bold>3<\/jats:bold> comprises a rare example of a non\u2010oxo vanadium(<jats:sc>IV<\/jats:sc>) species isolated from aqueous solution and in the presence of the reducing agent SO<jats:sub>3<\/jats:sub><jats:sup>2\u2212<\/jats:sup>, while compound <jats:bold>4<\/jats:bold> represents a rare example of an open\u2010framework species isolated at room temperature (20\u2009\u00b0C). In addition to the synthesis and crystallographic studies, we report the IR and magnetic properties (for <jats:bold>1<\/jats:bold>, <jats:bold>2<\/jats:bold> and <jats:bold>3<\/jats:bold>) of these vanadium clusters as well as theoretical studies on compound <jats:bold>3<\/jats:bold>.<\/jats:p>","DOI":"10.1002\/chem.200400203","type":"journal-article","created":{"date-parts":[[2005,2,1]],"date-time":"2005-02-01T03:49:11Z","timestamp":1107229751000},"page":"2295-2306","source":"Crossref","is-referenced-by-count":40,"title":["A Novel Series of Vanadium\u2010Sulfite Polyoxometalates: Synthesis, Structural, and Physical Studies"],"prefix":"10.1002","volume":"11","author":[{"given":"Haralampos N.","family":"Miras","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Raphael G.","family":"Raptis","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Nikolia","family":"Lalioti","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Michael P.","family":"Sigalas","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Peter","family":"Baran","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Themistoklis A.","family":"Kabanos","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2005,4,5]]},"reference":[{"key":"e_1_2_6_1_2","unstructured":"\u00a0"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19911030107"},{"key":"e_1_2_6_2_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.199100341"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1038\/352115b0"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr960395y"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1016\/S1387-7003(98)00029-X"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr9603946"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3765(20000403)6:7<1184::AID-CHEM1184>3.0.CO;2-B"},{"key":"e_1_2_6_8_2","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3765(20010917)7:18<3901::AID-CHEM3901>3.0.CO;2-3"},{"key":"e_1_2_6_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja036257p"},{"key":"e_1_2_6_10_2","doi-asserted-by":"publisher","DOI":"10.1038\/nature02036"},{"key":"e_1_2_6_11_2","volume-title":"Modular Chemistry","year":"1995"},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0010-8545(99)00170-8"},{"key":"e_1_2_6_13_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja001878t"},{"key":"e_1_2_6_14_2","volume-title":"Metal Oxide Chemistry and Synthesis: From Solution to Solid State","author":"Jolivet J. 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