{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,11,2]],"date-time":"2025-11-02T16:19:11Z","timestamp":1762100351461,"version":"build-2065373602"},"reference-count":34,"publisher":"Wiley","issue":"13","license":[{"start":{"date-parts":[[2005,4,13]],"date-time":"2005-04-13T00:00:00Z","timestamp":1113350400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2005,6,20]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>A new two\u2010phase route has been developed to synthesize high\u2010quality CdS nanocrystals with a narrow size distribution and a high photoluminescence (PL) quantum yield (QY). In the two\u2010phase system, toluene and water were used as separate solvents for cadmium myristate (CdM<jats:sub>2<\/jats:sub>) and thiourea, which served as cadmium source and sulfur source, respectively, and oleic acid (OA) was used as a ligand for stabilizing the nanocrystals. The reactions were completed in the heated autoclaves. The initial Cd\/S molar ratio of the precursors and the reaction temperature were found to be factors that affected the growth of nanocrystals. Furthermore, a seeding\u2010growth technique was developed to synthesize CdS nanocrystals of different sizes, which exhibit PL peaks with quite similar full width at half\u2010maximum (FWHM) values compared to those of the initial nanocrystal seeds in all cases.<\/jats:p>","DOI":"10.1002\/chem.200400993","type":"journal-article","created":{"date-parts":[[2005,4,13]],"date-time":"2005-04-13T11:42:13Z","timestamp":1113392533000},"page":"3843-3848","source":"Crossref","is-referenced-by-count":68,"title":["A New Two\u2010Phase Route to High\u2010Quality CdS Nanocrystals"],"prefix":"10.1002","volume":"11","author":[{"given":"Qiang","family":"Wang","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Daocheng","family":"Pan","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Shichun","family":"Jiang","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Xiangling","family":"Ji","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Lijia","family":"An","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Bingzheng","family":"Jiang","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2005,6,13]]},"reference":[{"key":"e_1_2_6_1_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.271.5251.933"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1038\/370354a0"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1038\/nature01217"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.366452"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-4095(199908)11:11<923::AID-ADMA923>3.0.CO;2-T"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1069156"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.290.5490.314"},{"key":"e_1_2_6_8_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.281.5385.2013"},{"key":"e_1_2_6_9_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.281.5385.2016"},{"key":"e_1_2_6_10_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.200305653"},{"key":"e_1_2_6_11_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00072a025"},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja9805425"},{"key":"e_1_2_6_13_2","doi-asserted-by":"publisher","DOI":"10.1021\/nl0155126"},{"key":"e_1_2_6_14_2","unstructured":"\u00a0"},{"key":"e_1_2_6_15_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja003633m"},{"key":"e_1_2_6_16_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja0173167"},{"key":"e_1_2_6_17_2","doi-asserted-by":"publisher","DOI":"10.1021\/nl0155532"},{"key":"e_1_2_6_18_2","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3757(20020703)114:13<2474::AID-ANGE2474>3.0.CO;2-#"},{"key":"e_1_2_6_18_3","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3773(20020703)41:13<2368::AID-ANIE2368>3.0.CO;2-G"},{"key":"e_1_2_6_19_2","doi-asserted-by":"publisher","DOI":"10.1021\/cm034729t"},{"key":"e_1_2_6_20_2","doi-asserted-by":"publisher","DOI":"10.1021\/j100082a044"},{"key":"e_1_2_6_21_2","doi-asserted-by":"publisher","DOI":"10.1021\/cm010709k"},{"key":"e_1_2_6_22_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja0123599"},{"key":"e_1_2_6_23_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja036683a"},{"key":"e_1_2_6_24_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja017002j"},{"key":"e_1_2_6_25_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp027160c"},{"key":"e_1_2_6_26_2","unstructured":"\u00a0"},{"key":"e_1_2_6_27_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.200400010"},{"journal-title":"Adv. Mater.","year":"2005","author":"Pan D. C.","key":"e_1_2_6_28_2"},{"key":"e_1_2_6_29_2","doi-asserted-by":"publisher","DOI":"10.1039\/C39940000801"},{"key":"e_1_2_6_30_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja0027766"},{"key":"e_1_2_6_31_2","doi-asserted-by":"publisher","DOI":"10.1351\/pac198860071107"},{"key":"e_1_2_6_32_2","doi-asserted-by":"publisher","DOI":"10.1021\/cm034081k"},{"key":"e_1_2_6_33_2","unstructured":"The preparation procedure of samples A\u2013E is described here. Sample A (initial nanocrystal seeds): CdM2(0.1134 g 0.2 mmol) in toluene (10 mL) thiourea (0.0304 g 0.4 mmol) in deionized water (10 mL) and oleic acid (1 mL) were mixed together and heated for 1 h. Sample B: CdM2(0.1134 g 0.2 mmol) in toluene (1 mL) thiourea (0.0076 g 0.1 mmol) in deionized water (10 mL) oleic acid (0.5 mL) 9 mL of the original oil phase containing sample A as seeds were mixed together and heated for 1 h. Sample C: CdM2(0.0340 g 0.06 mmol) in toluene (1 mL) thiourea (0.0457 g 0.6 mmol) in deionized water (10 mL) oleic acid (0.5 mL) 9 mL of the original oil phase containing sample B as seeds were mixed together and heated for 1.5 h. Sample D: CdM2(0.0567 g 0.1 mmol) in toluene (1 mL) thiourea (0.076 g 1 mmol) in deionized water (10 mL) oleic acid (0.5 mL) 9 mL of the original oil phase containing sample C as seeds were mixed together and heated for 1.5 h. Sample E: CdM2(0.0454 g 0.08 mmol) in toluene (1 mL) thiourea (0.0609 g 0.8 mmol) in deionized water (10 mL) oleic acid (0.5 mL) 9 mL of the original oil phase containing sample D as seeds were mixed together and heated for 1.5 h."}],"container-title":["Chemistry \u2013 A European Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fchem.200400993","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.200400993","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T22:04:10Z","timestamp":1760306650000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/chem.200400993"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2005,6,13]]},"references-count":34,"journal-issue":{"issue":"13","published-print":{"date-parts":[[2005,6,20]]}},"alternative-id":["10.1002\/chem.200400993"],"URL":"https:\/\/doi.org\/10.1002\/chem.200400993","archive":["Portico"],"relation":{},"ISSN":["0947-6539","1521-3765"],"issn-type":[{"type":"print","value":"0947-6539"},{"type":"electronic","value":"1521-3765"}],"subject":[],"published":{"date-parts":[[2005,6,13]]}}}