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All the complexes were characterized by elemental analysis, FT\u2010IR and NMR (<jats:sup>1<\/jats:sup>H, <jats:sup>13<\/jats:sup>C, <jats:sup>119<\/jats:sup>Sn) spectroscopy, TGA, and X\u2010ray crystallography diffraction analysis. The molecular structure analyses reveal that both <jats:bold>1<\/jats:bold> and <jats:bold>2<\/jats:bold> are hexanuclear macrocycles with hydrophobic \u201cpseudo\u2010cage\u201d structures, while <jats:bold>3<\/jats:bold> and <jats:bold>4<\/jats:bold> are hexanuclear macrocycles with double\u2010cavity structures. Furthermore, the supramolecular structure analyses show that looser and more intriguing supramolecular infrastructures were also found in complexes <jats:bold>1<\/jats:bold>\u2013<jats:bold>4<\/jats:bold>, which exist either as one\u2010dimensional chains of rings or as two\u2010dimensional networks assembled from the organometallic subunits through intermolecular C\uf8ffH\u22c5\u22c5\u22c5S weak hydrogen bonds (WHBs) and \u03c0\u2013\u03c0 interactions.<\/jats:p>","DOI":"10.1002\/chem.200500590","type":"journal-article","created":{"date-parts":[[2005,9,27]],"date-time":"2005-09-27T06:18:20Z","timestamp":1127801900000},"page":"420-428","source":"Crossref","is-referenced-by-count":81,"title":["Self\u2010Assembly of Dialkyltin Moieties and Mercaptobenzoic Acid into Macrocyclic Complexes with Hydrophobic \u201cPseudo\u2010Cage\u201d or Double\u2010Cavity Structures: Supramolecular Infrastructures Involving Intermolecular C\uf8ffH\u22c5\u22c5\u22c5S Weak Hydrogen Bonds and \u03c0\u2013\u03c0 Interactions"],"prefix":"10.1002","volume":"12","author":[{"given":"Chunlin","family":"Ma","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Qingfu","family":"Zhang","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Rufen","family":"Zhang","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Daqi","family":"Wang","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2005,12,19]]},"reference":[{"key":"e_1_2_6_1_2","unstructured":"For recent reviews see:"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0010-8545(02)00178-9"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3757(19990917)111:18<2798::AID-ANGE2798>3.0.CO;2-U"},{"key":"e_1_2_6_3_3","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3773(19990917)38:18<2638::AID-ANIE2638>3.0.CO;2-4"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1039\/a704290f"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3765(199801)4:1<19::AID-CHEM19>3.0.CO;2-D"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1007\/3-540-46591-X_6"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1007\/3-540-46591-X_5"},{"key":"e_1_2_6_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr990110s"},{"key":"e_1_2_6_9_2","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3757(20010601)113:11<2076::AID-ANGE2076>3.0.CO;2-S"},{"key":"e_1_2_6_9_3","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3773(20010601)40:11<2022::AID-ANIE2022>3.0.CO;2-D"},{"key":"e_1_2_6_10_2","doi-asserted-by":"publisher","DOI":"10.1021\/cm010176f"},{"key":"e_1_2_6_11_2","doi-asserted-by":"publisher","DOI":"10.1021\/cm011070n"},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr9900432"},{"key":"e_1_2_6_13_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200200551"},{"key":"e_1_2_6_13_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200200551"},{"key":"e_1_2_6_14_2","doi-asserted-by":"publisher","DOI":"10.1039\/b305705b"},{"key":"e_1_2_6_15_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200300588"},{"key":"e_1_2_6_15_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200300588"},{"key":"e_1_2_6_16_2","doi-asserted-by":"publisher","DOI":"10.1039\/B300512G"},{"key":"e_1_2_6_17_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0010-8545(98)00268-9"},{"key":"e_1_2_6_18_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0010-8545(01)00399-X"},{"key":"e_1_2_6_19_2","doi-asserted-by":"publisher","DOI":"10.1016\/0010-8545(95)01216-8"},{"key":"e_1_2_6_20_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0010-8545(00)00404-5"},{"key":"e_1_2_6_21_2","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.072065599"},{"key":"e_1_2_6_22_2","unstructured":"For recent reviews see:"},{"key":"e_1_2_6_23_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1071063"},{"key":"e_1_2_6_24_2","doi-asserted-by":"crossref","first-page":"139","DOI":"10.1002\/3527607439.ch9","volume-title":"Supramolecular Chemistry. 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