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The complex is stabilized by one C\u2010H\u22c5\u22c5\u22c5O\uf8feC and two C\u2010H\u22c5\u22c5\u22c5F\u2010C weak hydrogen bonds. The C\u2010H\u22c5\u22c5\u22c5O\uf8feC interaction, involving one carbonylic oxygen, is studied for the first time in detail with rotationally resolved spectroscopy. The two C\u2010H\u22c5\u22c5\u22c5F\u2010C weak hydrogen bonds involve two fluorine atoms of trifluoromethane and two hydrogens of the same methylenic group in the \u03b1 position.<\/jats:p>","DOI":"10.1002\/chem.200500674","type":"journal-article","created":{"date-parts":[[2005,10,14]],"date-time":"2005-10-14T04:46:48Z","timestamp":1129265208000},"page":"915-920","source":"Crossref","is-referenced-by-count":24,"title":["Molecular Beam Rotational Spectrum of Cyclobutanone\u2013Trifluoromethane: Nature of Weak CH\u22c5\u22c5\u22c5O\uf8feC and CH\u22c5\u22c5\u22c5F Hydrogen Bonds"],"prefix":"10.1002","volume":"12","author":[{"given":"Paolo","family":"Ottaviani","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Walther","family":"Caminati","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"L. 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