{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,27]],"date-time":"2026-09-27T07:25:15Z","timestamp":1790493915814,"version":"4.1.0"},"reference-count":44,"publisher":"Wiley","issue":"1","license":[{"start":{"date-parts":[[2005,10,12]],"date-time":"2005-10-12T00:00:00Z","timestamp":1129075200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2006,1]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>The two\u2010step one\u2010pot oxidative decarbonylation of [Fe<jats:sub>2<\/jats:sub>(S<jats:sub>2<\/jats:sub>C<jats:sub>2<\/jats:sub>H<jats:sub>4<\/jats:sub>)(CO)<jats:sub>4<\/jats:sub>(PMe<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>] (<jats:bold>1<\/jats:bold>) with [FeCp<jats:sub>2<\/jats:sub>]PF<jats:sub>6<\/jats:sub>, followed by addition of phosphane ligands, led to a series of diferrous dithiolato carbonyls <jats:bold>2<\/jats:bold>\u2013<jats:bold>6<\/jats:bold>, containing three or four phosphane ligands. In situ measurements indicate efficient formation of <jats:bold>1<\/jats:bold><jats:sup>2+<\/jats:sup> as the initial intermediate of the oxidation of <jats:bold>1<\/jats:bold>, even when a deficiency of the oxidant was employed. Subsequent addition of PR<jats:sub>3<\/jats:sub> gave rise to [Fe<jats:sub>2<\/jats:sub>(S<jats:sub>2<\/jats:sub>C<jats:sub>2<\/jats:sub>H<jats:sub>4<\/jats:sub>)(\u03bc\u2010CO)(CO)<jats:sub>3<\/jats:sub>(PMe<jats:sub>3<\/jats:sub>)<jats:sub>3<\/jats:sub>]<jats:sup>2+<\/jats:sup> (<jats:bold>2<\/jats:bold>) and [Fe<jats:sub>2<\/jats:sub>(S<jats:sub>2<\/jats:sub>C<jats:sub>2<\/jats:sub>H<jats:sub>4<\/jats:sub>)(\u03bc\u2010CO)(CO)<jats:sub>2<\/jats:sub>(PMe<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>(PR<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>]<jats:sup>2+<\/jats:sup> (R=Me <jats:bold>3<\/jats:bold>, OMe <jats:bold>4<\/jats:bold>) as principal products. One terminal CO ligand in these complexes was readily substituted by MeCN, and [Fe<jats:sub>2<\/jats:sub>(S<jats:sub>2<\/jats:sub>C<jats:sub>2<\/jats:sub>H<jats:sub>4<\/jats:sub>)(\u03bc\u2010CO)(CO)<jats:sub>2<\/jats:sub>(PMe<jats:sub>3<\/jats:sub>)<jats:sub>3<\/jats:sub>(MeCN)]<jats:sup>2+<\/jats:sup> (<jats:bold>5<\/jats:bold>) and [Fe<jats:sub>2<\/jats:sub>(S<jats:sub>2<\/jats:sub>C<jats:sub>2<\/jats:sub>H<jats:sub>4<\/jats:sub>)(\u03bc\u2010CO)(CO)(PMe<jats:sub>3<\/jats:sub>)<jats:sub>4<\/jats:sub>(MeCN)]<jats:sup>2+<\/jats:sup> (<jats:bold>6<\/jats:bold>) were fully characterized. Relevant to the H<jats:sub>red<\/jats:sub> state of the active site of Fe\u2010only hydrogenases, the unsymmetrical derivatives <jats:bold>5<\/jats:bold> and <jats:bold>6<\/jats:bold> feature a semibridging CO ligand <jats:italic>trans<\/jats:italic> to a labile coordination site.<\/jats:p>","DOI":"10.1002\/chem.200500752","type":"journal-article","created":{"date-parts":[[2005,10,12]],"date-time":"2005-10-12T09:49:43Z","timestamp":1129110583000},"page":"90-98","source":"Crossref","is-referenced-by-count":57,"title":["Electron\u2010Rich Diferrous\u2013Phosphane\u2013Thiolates Relevant to Fe\u2010only Hydrogenase: Is Cyanide \u201cNature's Trimethylphosphane\u201d?"],"prefix":"10.1002","volume":"12","author":[{"given":"Jarl Ivar","family":"van der Vlugt","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Thomas B.","family":"Rauchfuss","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Scott R.","family":"Wilson","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2005,12,9]]},"reference":[{"key":"e_1_2_6_1_2","doi-asserted-by":"publisher","DOI":"10.1002\/jlac.19284650106"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.19372330402"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1002\/1439-7633(20020301)3:2\/3<153::AID-CBIC153>3.0.CO;2-B"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0968-0004(99)01536-4"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1201\/9780203471043"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0010-8545(99)00251-9"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja0020963"},{"key":"e_1_2_6_8_2","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.0536955100"},{"key":"e_1_2_6_9_2","doi-asserted-by":"publisher","DOI":"10.1038\/nature03298"},{"key":"e_1_2_6_10_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja016516f"},{"key":"e_1_2_6_11_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic025838x"},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2005.01.013"},{"key":"e_1_2_6_13_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja992300q"},{"key":"e_1_2_6_14_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic0261225"},{"key":"e_1_2_6_15_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic025919t"},{"key":"e_1_2_6_16_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic50186a018"},{"key":"e_1_2_6_17_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0277-5387(00)80908-0"},{"key":"e_1_2_6_18_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-328X(00)98804-1"},{"key":"e_1_2_6_19_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00206a048"},{"key":"e_1_2_6_20_2","doi-asserted-by":"publisher","DOI":"10.1016\/0022-328X(91)86288-2"},{"key":"e_1_2_6_21_2","doi-asserted-by":"publisher","DOI":"10.1016\/0022-328X(91)83140-Y"},{"key":"e_1_2_6_22_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja049050k"},{"key":"e_1_2_6_23_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja051584d"},{"key":"e_1_2_6_24_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja9924187"},{"key":"e_1_2_6_25_2","first-page":"140","volume":"1","author":"Bardin J. 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