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Electron spin resonance (ESR) under irradiation with visible light (<jats:italic>\u03bb<\/jats:italic> \u2265 430 nm) afforded the increase in intensity in the visible\u2010light region. The concentration of trapped holes was about fourfold higher than that of trapped electrons. Nitrogen\u2010doped TiO<jats:sub>2<\/jats:sub> has been used to investigate mechanistically the photocatalytic oxidation of trichloroethylene (TCE) under irradiation with visible light (<jats:italic>\u03bb<\/jats:italic> \u2265 420 nm). Cl and O radicals, which contribute significantly to the generation of dichloroacetyl chloride (DCAC) in the photocatalytic oxidation of TCE under UV irradiation, were found to be deactivated under irradiation with visible light. As the main by\u2010product, only phosgene was detected in the photocatalytic oxidation of TCE under irradiation with visible light. Thus, the reaction mechanism of TCE photooxidation under irradiation with visible light clearly differs markedly from that under UV irradiation. Based on the results of the present study, we propose a new reaction mechanism and adsorbed species for the photocatalytic oxidation of TCE under irradiation with visible light. The energy band for TiO<jats:sub>2<\/jats:sub> by doping with nitrogen may involve an isolated band above the valence band.<\/jats:p>","DOI":"10.1002\/chem.200501020","type":"journal-article","created":{"date-parts":[[2006,3,20]],"date-time":"2006-03-20T06:16:45Z","timestamp":1142835405000},"page":"5526-5534","source":"Crossref","is-referenced-by-count":140,"title":["Mechanistic Studies of the Photocatalytic Oxidation of Trichloroethylene with Visible\u2010Light\u2010Driven N\u2010Doped TiO<sub>2<\/sub> Photocatalysts"],"prefix":"10.1002","volume":"12","author":[{"given":"Soon\u2010Kil","family":"Joung","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Takashi","family":"Amemiya","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Masayuki","family":"Murabayashi","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kiminori","family":"Itoh","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2006,7,7]]},"reference":[{"key":"e_1_2_6_1_2","doi-asserted-by":"crossref","first-page":"1200","DOI":"10.5796\/kogyobutsurikagaku.64.1200","volume":"64","author":"Kim J.","year":"1996","journal-title":"Denki Kagaku"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1155\/S1110662X01000101"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.tsf.2003.11.185"},{"key":"e_1_2_6_4_2","author":"Joung S.\u2010K.","journal-title":"Surf. 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