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Careful control of the crystallisation conditions of <jats:italic>C<\/jats:italic>\u2010methyl resorcinarene and 1,4\u2010dimethyl\u20101,4\u2010diazoniabicyclo[2.2.2]octane (1,4\u2010dimethyl DABCO) dibromide leads to a formation of two crystallographically different, but structurally very similar, solid\u2010state nanotube structures. These structures undergo a remarkable variety of supramolecular interactions, which lead to the formation of 0.5 nm diameter nonpolar tubes through the crystal lattice. The formation of these tubes is templated by suitably sized small alcohols, namely, <jats:italic>n<\/jats:italic>\u2010propanol, 2\u2010propanol, or <jats:italic>n<\/jats:italic>\u2010butanol. The self\u2010assembly involves close \u03c0<jats:bold>\u22c5\u22c5\u22c5<\/jats:bold>\u03c0 interactions between the adjacent resorcinarenes, and C\uf8ffH<jats:bold>\u22c5\u22c5\u22c5<\/jats:bold>\u03c0 and cation<jats:bold>\u22c5\u22c5\u22c5<\/jats:bold>\u03c0 interactions between the resorcinarenes and the guest 1,4\u2010dimethyl DABCO dications. The crystals of these supramolecular tube structures are thermally very stable and the included solvent alcohol can be removed from the tubes without breaking the single\u2010crystalline structure of the assembly. After removal of the solvent molecules the tubes can be filled with other small, less polar solvent molecules such as dichloromethane.<\/jats:p>","DOI":"10.1002\/chem.200501201","type":"journal-article","created":{"date-parts":[[2006,3,28]],"date-time":"2006-03-28T04:18:27Z","timestamp":1143519507000},"page":"4289-4296","source":"Crossref","is-referenced-by-count":50,"title":["Solvent Exchange in Thermally Stable Resorcinarene Nanotubes"],"prefix":"10.1002","volume":"12","author":[{"given":"Heidi","family":"Mansikkam\u00e4ki","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sara","family":"Busi","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Maija","family":"Nissinen","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Antti","family":"\u00c5hman","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kari","family":"Rissanen","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2006,5,17]]},"reference":[{"key":"e_1_2_6_1_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19951072105"},{"key":"e_1_2_6_1_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.199523111"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3757(20010316)113:6<1016::AID-ANGE10160>3.0.CO;2-8"},{"key":"e_1_2_6_2_3","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3773(20010316)40:6<988::AID-ANIE9880>3.0.CO;2-N"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1039\/b417413e"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-2860(03)00354-5"},{"key":"e_1_2_6_5_2","first-page":"973","volume":"78","author":"Utzig E.","year":"2004","journal-title":"J. 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