{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,5,12]],"date-time":"2026-05-12T17:25:35Z","timestamp":1778606735821,"version":"3.51.4"},"reference-count":44,"publisher":"Wiley","issue":"11","license":[{"start":{"date-parts":[[2007,1,10]],"date-time":"2007-01-10T00:00:00Z","timestamp":1168387200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2007,4,5]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>A facile <jats:sc>L<\/jats:sc>\u2010cysteine\u2010assisted route was designed for the selectively controlled synthesis of 1D and novel, interesting 3D CdS spherical nanostructures constructed from CdS nanorods (or nanopolypods) in a binary solution. By controlling reaction conditions such as the molar ratio between Cd(OAc)<jats:sub>2<\/jats:sub> and <jats:sc>L<\/jats:sc>\u2010cysteine and the volume ratio of the mixed solvents, the synthesis of various 3D architectural structures and 1D wirelike structures in large quantities can be controlled. This is the first reported case of the direct growth of novel 3D self\u2010assemblies of CdS nanorods (or nanopolypods). The morphology, structure, and phase composition of the as\u2010prepared CdS products were examined by using various techniques (X\u2010ray diffraction (XRD), field\u2010emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), selected\u2010area electron diffraction (SAED), high\u2010resolution TEM, and Raman spectroscopy). On the basis of the results from TEM studies and our analysis, we speculate that in the present synthesis the <jats:sc>L<\/jats:sc>\u2010cysteine dominates nucleation growth and the ethylenediamine (en)\u2010dominated, oriented\u2010assembly process. Interestingly, the products obtained show a gradient evolution in color from light\u2010yellow to dark\u2010yellow, which implies that their intrinsic optical properties change, possibly due to variations in their special morphologies and structures. This facile solution\u2010phase <jats:sc>L<\/jats:sc>\u2010cysteine\u2010assisted method could be extended for the controlled preparation of other metal chalcogenides nanostructures with complex morphologies.<\/jats:p>","DOI":"10.1002\/chem.200600786","type":"journal-article","created":{"date-parts":[[2007,1,10]],"date-time":"2007-01-10T04:17:40Z","timestamp":1168402660000},"page":"3076-3081","source":"Crossref","is-referenced-by-count":136,"title":["Shape\u2010Controlled Synthesis of 3D and 1D Structures of CdS in a Binary Solution with <scp>L<\/scp>\u2010Cysteine's Assistance"],"prefix":"10.1002","volume":"13","author":[{"given":"Shenglin","family":"Xiong","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Baojuan","family":"Xi","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Chengming","family":"Wang","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Guifu","family":"Zou","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Lifeng","family":"Fei","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Weizhi","family":"Wang","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yitai","family":"Qian","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2007,3,23]]},"reference":[{"key":"e_1_2_6_1_2","unstructured":"\u00a0"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0920-5861(00)00365-5"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1016\/0926-3373(95)00080-1"},{"key":"e_1_2_6_4_2","unstructured":"\u00a0"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.125172"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.1370993"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/nl025603i"},{"key":"e_1_2_6_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/nl025543g"},{"key":"e_1_2_6_9_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200250235"},{"key":"e_1_2_6_9_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200250235"},{"key":"e_1_2_6_10_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja0386389"},{"key":"e_1_2_6_11_2","doi-asserted-by":"publisher","DOI":"10.1038\/382609a0"},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1039\/b102319p"},{"key":"e_1_2_6_13_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.290.5499.2120"},{"key":"e_1_2_6_14_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1058120"},{"key":"e_1_2_6_15_2","doi-asserted-by":"publisher","DOI":"10.1038\/354056a0"},{"key":"e_1_2_6_16_2","unstructured":"\u00a0"},{"key":"e_1_2_6_17_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200463018"},{"key":"e_1_2_6_17_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200463018"},{"key":"e_1_2_6_18_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.200400177"},{"key":"e_1_2_6_19_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200390094"},{"key":"e_1_2_6_19_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200390126"},{"key":"e_1_2_6_20_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200500496"},{"key":"e_1_2_6_20_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200500496"},{"key":"e_1_2_6_21_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200460090"},{"key":"e_1_2_6_21_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200460090"},{"key":"e_1_2_6_22_2","unstructured":"\u00a0"},{"key":"e_1_2_6_23_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-4095(200004)12:7<520::AID-ADMA520>3.0.CO;2-#"},{"key":"e_1_2_6_24_2","doi-asserted-by":"publisher","DOI":"10.1002\/1521-4095(200009)12:18<1348::AID-ADMA1348>3.0.CO;2-X"},{"key":"e_1_2_6_25_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.200304758"},{"key":"e_1_2_6_26_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp051980i"},{"key":"e_1_2_6_27_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-4095(200006)12:11<808::AID-ADMA808>3.0.CO;2-P"},{"key":"e_1_2_6_28_2","doi-asserted-by":"publisher","DOI":"10.1002\/1521-4095(200010)12:20<1523::AID-ADMA1523>3.0.CO;2-T"},{"key":"e_1_2_6_29_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja0157595"},{"key":"e_1_2_6_30_2","doi-asserted-by":"publisher","DOI":"10.1002\/1521-4095(20021104)14:21<1537::AID-ADMA1537>3.0.CO;2-Q"},{"key":"e_1_2_6_31_2","first-page":"146","author":"Burford N.","journal-title":"Chem. 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