{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,30]],"date-time":"2026-09-30T20:55:42Z","timestamp":1790801742265,"version":"4.1.0"},"reference-count":56,"publisher":"Wiley","issue":"8","license":[{"start":{"date-parts":[[2006,12,11]],"date-time":"2006-12-11T00:00:00Z","timestamp":1165795200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2007,3,5]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>The core\u2010shell gold nanoparticles and copolymer of <jats:italic>N<\/jats:italic>\u2010isopropylacrylamide (NIPAM) and <jats:italic>N<\/jats:italic>,<jats:italic>N<\/jats:italic>\u2032\u2010methylenebisacrylamide (MBAA) hybrids (Au@copolymer) were fabricated through surface\u2010initiated atom\u2010transfer radical polymerization (ATRP) on the surface of gold nanoparticles in 2\u2010propanol\/water mixed solvents. The surface of citrate\u2010stabilized gold nanoparticles was first modified by a disulfide initiator for ATRP. The slight cross\u2010linking polymerization between NIPAM and MBAA occurred on the gold surface and resulted in the formation of core\u2010shell Au@copolymer nanostructures that were characterized by TEM, and FTIR and UV\u2010visible spectroscopy. Such synthesized Au@copolymer hybrids possess clearly thermosensitive properties and exhibit \u201cinspire\u201d and \u201cexpire\u201d water behavior in response to temperature changes in aqueous solution. Because of this property, we enable to trap and encapsulate smaller nanoparticles by using the free space of the copolymer\u2010network scaffold anchored at the gold surface.<\/jats:p>","DOI":"10.1002\/chem.200600839","type":"journal-article","created":{"date-parts":[[2006,12,11]],"date-time":"2006-12-11T04:19:55Z","timestamp":1165810795000},"page":"2224-2229","source":"Crossref","is-referenced-by-count":115,"title":["Thermosensitive Copolymer Networks Modify Gold Nanoparticles for Nanocomposite 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