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While compounds <jats:bold>I<\/jats:bold> and <jats:bold>II<\/jats:bold> are low dimensional, <jats:bold>III<\/jats:bold>\u2013<jats:bold>VI<\/jats:bold> have three\u2010dimensional structures. Compound <jats:bold>I<\/jats:bold> has edge\u2010shared ladders of iron phosphite with oxalate units hanging from the iron centers. Compound <jats:bold>II<\/jats:bold> has a layer structure with a honeycomb\u2010like arrangement. The three\u2010dimensional hybrid structures have the oxalate units connected in both in\u2010plane and out\u2010of\u2010plane modes. A newly identified secondary building unit (SBU\u20107) and the oxalate units satisfying the valence and coordination requirements in the structure of <jats:bold>V<\/jats:bold> are novel and noteworthy structural features. Magnetic studies show that the dominant interactions between the iron centers are antiferromagnetic. Similar to other known hybrid structures, the phosphite\u2013oxalate structures appear to show wide compositional and structural diversity.<\/jats:p>","DOI":"10.1002\/chem.200601026","type":"journal-article","created":{"date-parts":[[2006,10,25]],"date-time":"2006-10-25T12:28:52Z","timestamp":1161779332000},"page":"968-977","source":"Crossref","is-referenced-by-count":44,"title":["Inorganic\u2013Organic Hybrid Structures: Open\u2010Framework Iron Phosphite\u2013Oxalates of Varying Dimensionality"],"prefix":"10.1002","volume":"13","author":[{"given":"Sukhendu","family":"Mandal","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Srinivasan","family":"Natarajan","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2007,1,4]]},"reference":[{"key":"e_1_2_6_1_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3757(19991115)111:22<3466::AID-ANGE3466>3.0.CO;2-M"},{"key":"e_1_2_6_1_3","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3773(19991115)38:22<3268::AID-ANIE3268>3.0.CO;2-U"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic0346127"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1039\/b212181f"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200352219"},{"key":"e_1_2_6_4_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200352219"},{"key":"e_1_2_6_5_2","first-page":"1899","volume":"11","author":"Mandal S.","year":"2005","journal-title":"Current Science"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/cm0112845"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3757(20021004)114:19<3835::AID-ANGE3835>3.0.CO;2-N"},{"key":"e_1_2_6_7_3","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3773(20021004)41:19<3683::AID-ANIE3683>3.0.CO;2-J"},{"key":"e_1_2_6_8_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3765(20000403)6:7<1168::AID-CHEM1168>3.0.CO;2-S"},{"key":"e_1_2_6_9_2","doi-asserted-by":"publisher","DOI":"10.1039\/a906663b"},{"key":"e_1_2_6_10_2","doi-asserted-by":"publisher","DOI":"10.1021\/cm9903430"},{"key":"e_1_2_6_11_2","doi-asserted-by":"publisher","DOI":"10.1021\/cm021701t"},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1021\/cm0501968"},{"key":"e_1_2_6_13_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200300588"},{"key":"e_1_2_6_13_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200300588"},{"key":"e_1_2_6_14_2","doi-asserted-by":"publisher","DOI":"10.1006\/jssc.1998.7774"},{"key":"e_1_2_6_15_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jssc.2006.02.029"},{"key":"e_1_2_6_16_2","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3757(20020402)114:7<1272::AID-ANGE1272>3.0.CO;2-H"},{"key":"e_1_2_6_16_3","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3773(20020402)41:7<1224::AID-ANIE1224>3.0.CO;2-Z"},{"key":"e_1_2_6_17_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic990501p"},{"key":"e_1_2_6_18_2","doi-asserted-by":"publisher","DOI":"10.1021\/cm049064p"},{"key":"e_1_2_6_19_2","doi-asserted-by":"publisher","DOI":"10.1021\/cm990434x"},{"key":"e_1_2_6_20_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic030019d"},{"key":"e_1_2_6_21_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic050314t"},{"key":"e_1_2_6_22_2","doi-asserted-by":"publisher","DOI":"10.1039\/a910288o"},{"key":"e_1_2_6_23_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.solidstatesciences.2006.02.017"},{"key":"e_1_2_6_24_2","doi-asserted-by":"publisher","DOI":"10.1021\/cm011070n"},{"key":"e_1_2_6_25_2","doi-asserted-by":"publisher","DOI":"10.1006\/jssc.1999.8428"},{"key":"e_1_2_6_26_2","doi-asserted-by":"publisher","DOI":"10.1016\/S1293-2558(00)00146-1"},{"key":"e_1_2_6_27_2","unstructured":"SMART (Ver.\u20055.628) SAINT (Ver.\u20056.45a) XPREP SHELXTL Bruker AXS Inc. 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