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The pH value, reaction time, temperature, and molybdenian source have crucial influence on the phase formation, shape evolution, and microstructures. Monoclinic Fe<jats:sub>2<\/jats:sub>(MoO<jats:sub>4<\/jats:sub>)<jats:sub>3<\/jats:sub> particles obtained at pH\u20051 and pH\u20051.65 display ferromagnetic ordering at 10.4\u2005K and 10.5\u2005K, respectively, and the ferromagnetic component is determined to be 0.0458\u2005\u03bc<jats:sub>B<\/jats:sub> and 0.0349\u2005\u03bc<jats:sub>B<\/jats:sub> per Fe\u2010ion at 10\u2005K, respectively. For orthorhombic \u03b2\u2010Fe<jats:sub>2<\/jats:sub>(MoO<jats:sub>4<\/jats:sub>)<jats:sub>3<\/jats:sub>, antiferromagnetic ordering was observed about 12\u2005K. At higher temperatures, \u03b2\u2010Fe<jats:sub>2<\/jats:sub>(MoO<jats:sub>4<\/jats:sub>)<jats:sub>3<\/jats:sub> began to follow the Curie\u2013Weiss law with <jats:italic>\u03b8<\/jats:italic>=\u221270\u2005K. Such 3D architectures of monoclinic and orthorhombic \u03b2\u2010Fe<jats:sub>2<\/jats:sub>(MoO<jats:sub>4<\/jats:sub>)<jats:sub>3<\/jats:sub> microparticles with unique shapes and structural characteristics may find applications as catalysts and as well as in other fields.<\/jats:p>","DOI":"10.1002\/chem.200601426","type":"journal-article","created":{"date-parts":[[2006,12,8]],"date-time":"2006-12-08T04:48:53Z","timestamp":1165553333000},"page":"746-753","source":"Crossref","is-referenced-by-count":124,"title":["3D Architectures of Iron Molybdate: Phase Selective Synthesis, Growth Mechanism, and Magnetic Properties"],"prefix":"10.1002","volume":"13","author":[{"given":"Yi","family":"Ding","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Shu\u2010Hong","family":"Yu","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Chen","family":"Liu","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Zheng\u2010An","family":"Zang","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2007,1,4]]},"reference":[{"key":"e_1_2_6_1_2","unstructured":"\u00a0"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1039\/b105058n"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1002\/352760247X"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.200390087"},{"key":"e_1_2_6_5_2","unstructured":"\u00a0"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1124005"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/nl060235u"},{"key":"e_1_2_6_8_2","doi-asserted-by":"publisher","DOI":"10.1038\/nmat908"},{"key":"e_1_2_6_9_2","unstructured":"\u00a0"},{"key":"e_1_2_6_10_2","doi-asserted-by":"publisher","DOI":"10.1038\/nmat902"},{"key":"e_1_2_6_11_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp0265485"},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1021\/nl025753t"},{"key":"e_1_2_6_13_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja034327m"},{"key":"e_1_2_6_14_2","unstructured":"\u00a0"},{"key":"e_1_2_6_15_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja003633m"},{"key":"e_1_2_6_16_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja0459678"},{"key":"e_1_2_6_17_2","doi-asserted-by":"publisher","DOI":"10.1002\/1521-4095(20021104)14:21<1537::AID-ADMA1537>3.0.CO;2-Q"},{"key":"e_1_2_6_18_2","unstructured":"\u00a0"},{"key":"e_1_2_6_19_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja044825a"},{"key":"e_1_2_6_20_2","doi-asserted-by":"publisher","DOI":"10.1002\/smll.200500193"},{"key":"e_1_2_6_21_2","doi-asserted-by":"publisher","DOI":"10.1021\/nl0503072"},{"key":"e_1_2_6_22_2","doi-asserted-by":"publisher","DOI":"10.1021\/cm048436r"},{"key":"e_1_2_6_23_2","doi-asserted-by":"publisher","DOI":"10.1021\/cm060956u"},{"key":"e_1_2_6_24_2","unstructured":"\u00a0"},{"key":"e_1_2_6_25_2","first-page":"2414","volume":"14","author":"Yu S. 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