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In these compounds, the stability of the metal\u2013borane linkage was enhanced by increasing the electron\u2010releasing ability of the substituent on boron. A stronger base L additionally stabilized the complexes. The strength of the borane\u2013metal interaction is thus mainly ascribed to the electron donation from the BH \u03c3 orbital to metal rather than the back\u2010donation into the BH \u03c3* orbital. This result supports the bonding model for the B\u2010H\u2010M linkage in the borane complexes suggested by MO calculations, where the borane\u2010to\u2010metal electron donation is predominant while the metal back\u2010donation into the BH \u03c3* orbital is negligible. Such a stability trend of the borane complexes makes a sharp contrast to that of many silane and dihydrogen complexes.<\/jats:p>","DOI":"10.1002\/chem.200601883","type":"journal-article","created":{"date-parts":[[2007,5,25]],"date-time":"2007-05-25T11:29:55Z","timestamp":1180092595000},"page":"6920-6931","source":"Crossref","is-referenced-by-count":74,"title":["Investigation of the Stability of the M\u2010H\u2010B Bond in Borane \u03c3 Complexes [M(CO)<sub>5<\/sub>(\u03b7<sup>1<\/sup>\u2010BH<sub>2<\/sub>R\u22c5L)] and [CpMn(CO)<sub>2<\/sub>(\u03b7<sup>1<\/sup>\u2010BH<sub>2<\/sub>R\u22c5L)] (M=Cr, W; L=Tertiary Amine or Phosphine): Substituent and Lewis Base Effects"],"prefix":"10.1002","volume":"13","author":[{"given":"Yasuro","family":"Kawano","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kazunori","family":"Yamaguchi","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shun\u2010ya","family":"Miyake","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Taeko","family":"Kakizawa","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mamoru","family":"Shimoi","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2007,8,7]]},"reference":[{"key":"e_1_2_6_1_2","unstructured":"Some reviews of metallaborane clusters"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1039\/cs9952400215"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1039\/cs9922100049"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic030279v"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1039\/a800924d"},{"key":"e_1_2_6_6_2","unstructured":"Recent reviews of non\u2010classical transition metal\u2013boron compounds"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0010-8545(01)00378-2"},{"key":"e_1_2_6_8_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2003.12.003"},{"key":"e_1_2_6_9_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200500054"},{"key":"e_1_2_6_9_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200500054"},{"key":"e_1_2_6_10_2","first-page":"293","volume-title":"Current Topics in the Chemistry of Boron","author":"Shimoi M.","year":"1994"},{"key":"e_1_2_6_11_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja990828p"},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1021\/om0102697"},{"key":"e_1_2_6_13_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200219992"},{"key":"e_1_2_6_13_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200219992"},{"key":"e_1_2_6_14_2","doi-asserted-by":"publisher","DOI":"10.1021\/om0604324"},{"key":"e_1_2_6_15_2","unstructured":"\u00a0"},{"key":"e_1_2_6_16_2","first-page":"1999","volume":"121","author":"Kawano Y.","year":"1999","journal-title":"J. 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