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These structures are, [Cd<jats:sup>II<\/jats:sup>{(<jats:italic>R<\/jats:italic>)\u2010AAP}(Py)(H<jats:sub>2<\/jats:sub>O)]<jats:bold>\u22c5<\/jats:bold>(ClO<jats:sub>4<\/jats:sub>), (<jats:italic>R<\/jats:italic>)\u2010<jats:bold>1<\/jats:bold>; [Cd<jats:sup>II<\/jats:sup>{(<jats:italic>S<\/jats:italic>)\u2010AAP}(H<jats:sub>2<\/jats:sub>O)<jats:sub>2<\/jats:sub>]<jats:bold>\u22c5<\/jats:bold>(ClO<jats:sub>4<\/jats:sub>), (<jats:italic>S<\/jats:italic>)\u2010<jats:bold>2<\/jats:bold>; [Zn<jats:sub>2<\/jats:sub><jats:sup>II<\/jats:sup>{(<jats:italic>R<\/jats:italic>,<jats:italic>S<\/jats:italic>)\u2010AMPA}(H<jats:sub>2<\/jats:sub>O)], (<jats:italic>R<\/jats:italic>,<jats:italic>S<\/jats:italic>)\u2010<jats:bold>3<\/jats:bold>; [Zn<jats:sub>2<\/jats:sub><jats:sup>II<\/jats:sup>{(<jats:italic>R<\/jats:italic>)\u2010ACP}(Py)<jats:sub>3<\/jats:sub>]<jats:bold>\u22c5<\/jats:bold>(ClO<jats:sub>4<\/jats:sub>)<jats:sub>2<\/jats:sub>, (<jats:italic>R<\/jats:italic>)\u2010<jats:bold>4<\/jats:bold>; and the inversion twin of (<jats:italic>R<\/jats:italic>)\u2010<jats:bold>1<\/jats:bold>. 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