{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,18]],"date-time":"2026-09-18T09:30:37Z","timestamp":1789723837444,"version":"4.0.1"},"reference-count":24,"publisher":"Wiley","issue":"33","license":[{"start":{"date-parts":[[2007,8,20]],"date-time":"2007-08-20T00:00:00Z","timestamp":1187568000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2007,11,16]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Layering solutions of P<jats:sub>4<\/jats:sub>S<jats:sub>3<\/jats:sub> in CH<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub> with solutions of CuCl or CuI in CH<jats:sub>3<\/jats:sub>CN gives the coordination polymers (P<jats:sub>4<\/jats:sub>S<jats:sub>3<\/jats:sub>)<jats:sub>3<\/jats:sub>(CuCl)<jats:sub>7<\/jats:sub> (<jats:bold>1<\/jats:bold>), (P<jats:sub>4<\/jats:sub>S<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>(CuCl)<jats:sub>3<\/jats:sub> (<jats:bold>2<\/jats:bold>), (P<jats:sub>4<\/jats:sub>S<jats:sub>3<\/jats:sub>)(CuI) (<jats:bold>3<\/jats:bold>) and (P<jats:sub>4<\/jats:sub>S<jats:sub>3<\/jats:sub>)(CuI)<jats:sub>3<\/jats:sub> (<jats:bold>4<\/jats:bold>), respectively, after slow diffusion. The yellow compounds were characterised by elemental analysis, <jats:sup>31<\/jats:sup>P magic\u2010angle spinning (MAS) NMR spectroscopy and single\u2010crystal X\u2010ray crystallography. The solid\u2010state structures demonstrate the unexpected ligand versatility of the P<jats:sub>4<\/jats:sub>S<jats:sub>3<\/jats:sub> molecule, which interacts through two, three, or even all of the phosphorus atoms with copper according to the nature of the copper halide. Compound <jats:bold>1<\/jats:bold> has a three\u2010dimensional network in which linear and cylindrical infinite CuCl subunits coexist with diatomic CuCl building blocks. For the first time, all four P atoms of the P<jats:sub>4<\/jats:sub>S<jats:sub>3<\/jats:sub> cage are involved in coordination with metal atoms. The 3D structure of <jats:bold>2<\/jats:bold> contains stacks of P<jats:sub>4<\/jats:sub>S<jats:sub>3<\/jats:sub> that are interconnected by slightly undulated and planar [CuCl]<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub> ribbons. Compound <jats:bold>3<\/jats:bold> is a one\u2010dimensional polymer composed of alternating (CuI)<jats:sub>2<\/jats:sub> rings and P<jats:sub>4<\/jats:sub>S<jats:sub>3<\/jats:sub> bridges. The structure of <jats:bold>4<\/jats:bold> consists of undulated [CuI]<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub> layers in which the P<jats:sub>4<\/jats:sub>S<jats:sub>3<\/jats:sub> cage functions as a bridge within the layer, as well as a spacer between the layers. The <jats:sup>31<\/jats:sup>P\u2005MAS\u2005NMR spectra obtained are in good agreement with the solid\u2010state structures obtained crystallographically. Thus, analytically pure <jats:bold>3<\/jats:bold> and <jats:bold>4<\/jats:bold> show singlet peaks that correspond to uncoordinated P and quartets owing to coupling with <jats:sup>63<\/jats:sup>Cu and <jats:sup>65<\/jats:sup>Cu, respectively, whereas that of <jats:bold>1<\/jats:bold> contains quartets according to all\u2010P coordination. The spectrum of <jats:bold>2<\/jats:bold> was obtained from a sample that still contained 40\u2009% of <jats:bold>1<\/jats:bold>.<\/jats:p>","DOI":"10.1002\/chem.200700761","type":"journal-article","created":{"date-parts":[[2007,8,20]],"date-time":"2007-08-20T03:18:30Z","timestamp":1187579910000},"page":"9270-9276","source":"Crossref","is-referenced-by-count":33,"title":["The Unexpected Versatility of P<sub>4<\/sub>S<sub>3<\/sub> as a Building Block in Polymeric Copper Halide Networks: 2,3\u2010P, 1,2,3\u2010P and all\u2010P Coordination"],"prefix":"10.1002","volume":"13","author":[{"given":"Andreas","family":"Biegerl","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Eike","family":"Brunner","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Christian","family":"Gr\u00f6ger","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Manfred","family":"Scheer","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Joachim","family":"Wachter","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Manfred","family":"Zabel","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2007,11,8]]},"reference":[{"key":"e_1_2_6_1_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic50131a025"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1039\/c29690000536"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-328X(00)99283-0"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic00157a020"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic001384x"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/bk-1983-0232.ch002"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic010559f"},{"key":"e_1_2_6_8_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.200300473"},{"key":"e_1_2_6_9_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jorganchem.2003.09.048"},{"key":"e_1_2_6_10_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja012760v"},{"key":"e_1_2_6_11_2","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.19774320135"},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3765(20020916)8:18<4228::AID-CHEM4228>3.0.CO;2-V"},{"key":"e_1_2_6_13_2","unstructured":"\u00a0"},{"key":"e_1_2_6_14_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3749(199912)625:12<2196::AID-ZAAC2196>3.0.CO;2-E"},{"key":"e_1_2_6_15_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic981042f"},{"key":"e_1_2_6_16_2","doi-asserted-by":"publisher","DOI":"10.1524\/zkri.1983.165.1-4.47"},{"key":"e_1_2_6_17_2","first-page":"971","author":"Healy P. C.","year":"1988","journal-title":"J. Chem. Soc. Dalton Trans."},{"key":"e_1_2_6_18_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-4596(02)00049-X"},{"key":"e_1_2_6_19_2","unstructured":"Unpublished results."},{"key":"e_1_2_6_20_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic049164x"},{"key":"e_1_2_6_21_2","doi-asserted-by":"publisher","DOI":"10.1039\/dt9890000809"},{"key":"e_1_2_6_22_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200600690"},{"key":"e_1_2_6_22_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200600690"},{"key":"e_1_2_6_23_2","doi-asserted-by":"publisher","DOI":"10.1002\/mrc.984"}],"container-title":["Chemistry \u2013 A European Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fchem.200700761","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.200700761","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T18:10:49Z","timestamp":1760292649000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/chem.200700761"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2007,11,8]]},"references-count":24,"journal-issue":{"issue":"33","published-print":{"date-parts":[[2007,11,16]]}},"alternative-id":["10.1002\/chem.200700761"],"URL":"https:\/\/doi.org\/10.1002\/chem.200700761","archive":["Portico"],"relation":{},"ISSN":["0947-6539","1521-3765"],"issn-type":[{"value":"0947-6539","type":"print"},{"value":"1521-3765","type":"electronic"}],"subject":[],"published":{"date-parts":[[2007,11,8]]}}}