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The dissociation Gibbs free energies of these \u201ccomplexes\u201d were calculated by using density functional theory (B3LYP\/3\u201021G(*) and B3LYP\/6\u2010311+G**). The dissociation Gibbs free energies show systematic dependence on the phosphorus substituent as well as on the stability of the N\u2010donor ligand formed as a byproduct. The thermodynamics and kinetics of the dissociations were thoroughly examined. The results allow us to conclude that novel routes of phosphinidene generation can be developed.<\/jats:p>","DOI":"10.1002\/chem.200701077","type":"journal-article","created":{"date-parts":[[2007,10,22]],"date-time":"2007-10-22T11:15:47Z","timestamp":1193051747000},"page":"902-908","source":"Crossref","is-referenced-by-count":15,"title":["A Promising Method for Phosphinidene Generation: Complexes of Phosphinidenes with N\u2010Donor ligands"],"prefix":"10.1002","volume":"14","author":[{"given":"Zolt\u00e1n","family":"Benk\u00f5","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Dietrich","family":"Gudat","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"L\u00e1szl\u00f3","family":"Nyul\u00e1szi","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2008,1,10]]},"reference":[{"key":"e_1_2_6_1_2","unstructured":"The first push push carbene the imidazol\u20102\u2010ylidene has been reported by"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00001a054"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00227a028"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19891010513"},{"key":"e_1_2_6_4_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.198906211"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr940472u"},{"key":"e_1_2_6_6_2","doi-asserted-by":"crossref","first-page":"1794","DOI":"10.1002\/ange.200301729","volume":"116","author":"Kirmse W.","year":"2004","journal-title":"Angew. 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