{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,14]],"date-time":"2025-10-14T01:12:13Z","timestamp":1760404333676,"version":"build-2065373602"},"reference-count":41,"publisher":"Wiley","issue":"36","license":[{"start":{"date-parts":[[2007,10,19]],"date-time":"2007-10-19T00:00:00Z","timestamp":1192752000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2007,12,17]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>The synthesis of the crown\u2010ether\u2010substituted bis(organostannyl)methanes Ph<jats:sub>3<\/jats:sub>SnCH<jats:sub>2<\/jats:sub>Sn(Ph<jats:sub>2<\/jats:sub>)\u2010CH<jats:sub>2<\/jats:sub>\u2010[16]crown\u20105 (<jats:bold>1<\/jats:bold>) and Ph<jats:sub>2<\/jats:sub>ISnCH<jats:sub>2<\/jats:sub>Sn(I)(Ph)\u2010CH<jats:sub>2<\/jats:sub>\u2010[16]crown\u20105 (<jats:bold>2<\/jats:bold>) is reported. Both compounds have been characterized by elemental analyses, <jats:sup>1<\/jats:sup>H, <jats:sup>13<\/jats:sup>C, <jats:sup>19<\/jats:sup>F, and <jats:sup>119<\/jats:sup>Sn\u2005NMR spectroscopy, and in the case of compound <jats:bold>2<\/jats:bold> also by electrospray ionization mass spectrometry. Single\u2010crystal X\u2010ray diffraction analysis revealed for the aqua complex <jats:bold>2\u22c5<\/jats:bold>H<jats:sub>2<\/jats:sub>O trigonal\u2013bipyramidal\u2010configured tin atoms with intramolecular Sn(1)\uf8ffO(1) and Sn(2)\uf8ffO(1W) distances of 2.555(2) and 2.440(3)\u2005\u00c5, respectively. The water molecule is trapped in a sandwich\u2010like fashion between the crown ether oxygen atoms O(2) and O(4) and the Sn(2) atom. NMR spectroscopy unambiguously proved the ability of compound <jats:bold>2<\/jats:bold> in acetonitrile to overcome the high lattice energy of sodium fluoride and to complex the latter under charge separation.<\/jats:p>","DOI":"10.1002\/chem.200701141","type":"journal-article","created":{"date-parts":[[2007,10,19]],"date-time":"2007-10-19T07:14:19Z","timestamp":1192778059000},"page":"10239-10245","source":"Crossref","is-referenced-by-count":45,"title":["Solubilizing Sodium Fluoride in Acetonitrile: Synthesis, Molecular Structure, and Complexation Behavior of Bis(organostannyl)methyl\u2010Substituted Crown Ethers"],"prefix":"10.1002","volume":"13","author":[{"given":"Gregor","family":"Reeske","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Gerrit","family":"Bradtm\u00f6ller","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Markus","family":"Sch\u00fcrmann","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Klaus","family":"Jurkschat","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2007,12,7]]},"reference":[{"key":"e_1_2_6_1_2","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3757(20010202)113:3<502::AID-ANGE502>3.0.CO;2-A"},{"key":"e_1_2_6_1_3","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3773(20010202)40:3<486::AID-ANIE486>3.0.CO;2-P"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1039\/b515634c"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1039\/b302141f"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200590055"},{"key":"e_1_2_6_4_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200462945"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0010-8545(03)00022-5"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja0156082"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic049066b"},{"key":"e_1_2_6_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic0494859"},{"key":"e_1_2_6_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja0440295"},{"key":"e_1_2_6_10_2","doi-asserted-by":"publisher","DOI":"10.1039\/B515458H"},{"key":"e_1_2_6_11_2","doi-asserted-by":"publisher","DOI":"10.1039\/b415189e"},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1039\/B609180F"},{"key":"e_1_2_6_13_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19911031123"},{"key":"e_1_2_6_13_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.199114741"},{"key":"e_1_2_6_14_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19911031124"},{"key":"e_1_2_6_14_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.199114721"},{"key":"e_1_2_6_15_2","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3765(20011105)7:21<4686::AID-CHEM4686>3.0.CO;2-7"},{"key":"e_1_2_6_16_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.200500191"},{"key":"e_1_2_6_17_2","doi-asserted-by":"publisher","DOI":"10.1021\/om700304p"},{"key":"e_1_2_6_18_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.200300780"},{"key":"e_1_2_6_19_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-328X(00)90195-5"},{"key":"e_1_2_6_20_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic00098a019"},{"key":"e_1_2_6_21_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.200390022"},{"key":"e_1_2_6_22_2","doi-asserted-by":"publisher","DOI":"10.1016\/0022-328X(84)80544-6"},{"key":"e_1_2_6_23_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1099-0682(199905)1999:5<887::AID-EJIC887>3.0.CO;2-2"},{"key":"e_1_2_6_24_2","doi-asserted-by":"publisher","DOI":"10.1021\/om00059a053"},{"volume-title":"Handbook of Chemistry and Physics","year":"2000","author":"Lide D. 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